phase change of water from liquid to gas at 25.0°C. H2O (l)   -->  H2O (g)   b) Is this phase change spontaneous at 25.0°C?  Give the reason for your answer. c) Find the temperature at which this phase change becomes spontaneous.  Give in both

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

a) Find DHrxn, DSrxn, and DGrxn phase change of water from liquid to gas at 25.0°C.

H2O (l)   -->  H2O (g)  

b) Is this phase change spontaneous at 25.0°C?  Give the reason for your answer.

c) Find the temperature at which this phase change becomes spontaneous.  Give in both K and ℃.

 

 

A-6
Appendix B • Standard Thermodynamic Values for Selected Substances
Appendix B. Standard Thermodynamic Values for Selected Substances
А-7
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
Substance
AH;
(kJ/mol)
AG;
(kJ/mol)
S°
or lon
(J/mol-K)
or lon
(J/mol-K)
or lon
(J/mol-K)
or lon
(J/mol-K)
CCl,(1)
COCI2(8)
Cesium
Cs(s)
Cs(g)
Cs*(g)
Cs*(aq)
CsF(s)
CSCI(s)
CsBr(s)
CsI(s)
-68.6
-206
-139
214.4
FeCl3(s)
FeO(s)
Fe,03(s)
Fe;O4(s)
-399.5
AgF(s)
AgCl(s)
AgBr(s)
AgI(s)
AGNO3(s)
Ag,S(s)
Sodium
-334.1
142
155.6
-203
-185
84
HNO3(1)
HNO3(aq)
NF3(g)
NOCI(g)
NH,CI(s)
Охудen
O2(g)
O(g)
03(8)
ОН (ад)
H,O(g)
H2O(1)
H,O2(1)
H,O,(aq)
Phosphorus
P4(s, white)
P(g)
P(s, red)
P2(8)
PĄ(8)
PCI3(8)
PCI3(1)
PCI5(g)
PCI3(s)
P,O10(s)
PO (aq)
НРО (ад)
H,PO, (aq)
H;PO4(aq)
H;PO,(1)
Potassium
-173.23
-79.914
-220
283.74
-272.0
-251.4
-206.57
-110.5
146
-127.03
-109.72
96.11
60.75
87.400
145.3
-825.5
-743.6
-95.939
-66.32
-125
-83.3
260.6
-99.51
107.1
85.15
-1121
-1018
51.71
66.07
261.6
-62.38
114
76.7
49.7
175.5
Lead
94.6
-45.06
19.1
-40.3
-314.4
-203.0
128.2
458.5
427.1
169.72
Pb(s)
Pb*(aq)
PbCl2(s)
PbO(s)
PbO2(s)
PbS(s)
PbSO,(s)
-31.8
146
64.785
21
-248
-282.0
133
1.6
-24.3
205.0
-554.7
-525.4
88
-359
-314
249.2
231.7
160.95
Na(s)
Na(g)
Na*(g)
Na*(aq)
NaF(s)
NaCl(s)
NaBr(s)
NaOH(s)
Na,CO3(s)
NaHCO3(s)
NaI(s)
Strontium
136
51.446
-442.8
-395
-414
101.18
-218
-198
68.70
143
163
238.82
107.76
77.299
153.61
-383
121
-276.6
-219.0
-157.30
-228.60
76.6
-229.94
-10.54
609.839
574.877
147.85
-337
-333
130
-98.3
-96.7
91.3
-241.826
188.72
-239.66
-261.87
60.2
Chlorine
-918.39
-811.24
147
-285.840
-237.192
69.940
-575.4
-545.1
51.21
Cl2(g)
Cl(g)
CI"(g)
CI"(aq)
HCI(g)
HCI(aq)
CIO2(g)
Cl,0(g)
Chromium
223.0
Lithium
-187.8
-120.4
110
-411.1
-384.0
72.12
121.0
105.0
165.1
Li(s)
Li(g)
Li*(8)
Li*(aq)
LiF(s)
LİCI(s)
LiBr(s)
LiI(s)
Magnesium
Mg(s)
Mg(g)
Mg**(g)
Mg**(aq)
MgCl2(s)
MGCO3(s)
MgO(s)
Mg;N2(s)
Manganese
Mn(s, c)
Mn*(aq)
MnOg(s)
MnO, (aq)
Mercury
Hg(1)
Hg(g)
Hg²*(aq)
Hg*(aq)
HgCl½(s)
Hg,Cl,(s)
HgO(s)
Nitrogen
N2(g)
N(g)
N20(g)
NO(g)
NO2(g)
N,O3(g)
N204(8)
N2O5(g)
N,O5(s)
NH3(g)
NH3(aq)
N2H4(1)
NO (aq)
144
-349
86.82
29.10
138.67
132.91
-191.2
-134.1
-361
-234
-240
153.25
161
128
-425.609
-379.53
64.454
-167.46
-131.17
55.10
687.163
649.989
41.1
-1130.8
-1048.1
139
-92.31
-95.30
186.79
-278.46
-293.8
14
314.6
278.3
163.1
-947.7
-851.9
102
-167.46
-131.17
55.06
-616.9
-588.7
-384
35.66
-17.6
-12.1
22.8
-288
-285
98.5
102
120
256.7
-408
59.30
144
104
218
80.3
97.9
266.1
-351
-342
Sr(s)
Sr(g)
Sr*(g)
Sr*(aq)
SrCl2(s)
SrCO3(s)
SrO(s)
SrSO,(s)
Sulfur
74.1
58.9
24.5
280
54.4
-270
-270
85.8
-287
-268
312
164
110
164.54
Cr(s)
Cr**(aq)
Cro (aq)
Cr,O (aq)
Сopper
Cu(s)
Cu(g)
Cu*(aq)
Cu²*(aq)
Cu,O(s)
CuO(s)
Cu,S(s)
CuS(s)
Fluorine
23.8
-320
-272
217
1784
-1971
32.69
-402
-443.5
-2984
-323
353
-545.51
-557.3
-39
-863.2
-706.3
38
150
115
148.55
-828.4
-781.2
117
-1461
-1257
214
2351
-2698
229
-1218
-1138
97.1
-461.96
-456.01
118
-1266
-1013
-218
-592.0
-562.4
55.5
33.1
-641.6
-592.1
89.630
-1281
-1082
-36
-1445
-1334
122
341.1
301.4
166.29
-1112
-1028
65.86
26.9
-1285
-1135
89.1
51.9
64.39
50.2
-26
S(rhombic)
S(monoclinic)
S(g)
S2(g)
S8(g)
s (aq)
HS¯(aq)
H,S(g)
H,S(aq)
SO2(g)
SO:(8)
SO (aq)
HSO,(aq)
H;SO,(1)
H,SO4(aq)
-601.2
-461
-569.0
-1277
-1019
228
31.9
64.98
-98.7
-401
88
-1271.7
-1123.6
150.8
0.3
0.096
32.6
-168.6
-146.0
93.1
279
239
168
-157.3
-130
42.63
31.8
64.672
129
80.1
228.1
K(s)
K(g)
K*(g)
K*(aq)
KF(s)
KCI(s)
KBr(s)
KI(s)
КОН(:)
KCIO;(s)
KCIO:(s)
-79.5
-86.2
120.9
-219
-223
-84
89.2
60.7
160.23
101
49.1
430.211
-53.1
-53.6
66.5
-520.9
-466.1
53.1
514.197
481.202
154.47
41.8
83.7
22
-518.4
-425.1
190
-251.2
-282.28
103
-17.7
12.6
61.1
F2(g)
F(g)
F (g)
F (aq)
HF(g)
Hydrogen
H2(g)
H(g)
H*(aq)
H*(g)
202.7
-568.6
-538.9
66.55
-20.2
-33
205.6
78.9
61.8
158.64
76.027
-436.7
-409.2
82.59
-39
-27.4
122
-255.6
-262.5
145.47
61.30
31.8
174.87
-394
-380
95.94
-296.8
-300.2
248.1
-329.1
-276.5
-9.6
171
164.4
-32
-328
-323
106.39
-396
-371
256.66
-273
-275
173.67
172
153.6
84.5
-424.8
-379.1
78.87
-907.51
-741.99
17
-230
-264.9
-885.75
-813.989
-184
144
-397.7
-296.3
143.1
-752.87
126.9
0.
130.6
-210.66
196
-432.75
-303.2
151.0
-690.059
156.90
218.0
203.30
114.60
-90.79
-58.50
70.27
Rubidium
-907.51
-741.99
17
Rb(s)
Rb(g)
Rb*(g)
Rb*(aq)
RbF(s)
RbCl(s)
RbBr(s)
RbI(s)
Silicon
69.5
Tin
1536.3
1517.1
108.83
191.5
153.2
Sn(white)
Sn(gray)
SnCl,(1)
SnO2(s)
Titanium
85.81
55.86
169.99
51.5
Iodine
473
456
495.04
3
4.6
44.8
L(s)
L(8)
I(g)
I(g)
I(aq)
HI(g)
-116.14
82.05
104.2
219.7
-246
-282.2
124
-545.2
-474.0
259
62.442
19.38
70.21
260.58
90.29
86.60
210.65
-549.28
-580.7
-519.7
52.3
106.8
180.67
33.2
51
239.9
-435.35
-407.8
95.90
-194.7
86.6
142.4
314.7
108.3
Ti(s)
TiCl,(1)
TiO2(s)
-389.2
-378.1
30.7
-55.94
-51.67
109.4
304.3
346
9.16
97.7
-328
-326
118.0
-804.2
-737.2
252.3
25.9
1.3
206.33
11
118
-944.0
-888.8
50.6
Iron
-43.1
114
178
Zinc
Si(s)
SiF,(g)
SiO2(s)
0.
18.0
Fe(s)
Fe*(aq)
Fe*(aq)
FeCl2(s)
27.3
193
110
-45.9
-16
-1614.9
-1572.7
282.4
Zn(s)
41.6
-47.7
-10.5
-293
-80.83
26.7
160.9
Zn(g)
Zn²*(aq)
ZnO(s)
ZnS(s, zinc
blende)
-910.9
-856.5
41.5
130.5
94.93
-87.9
-84.94
113
50.63
149.2
121.2
Silver
-152.4
-147.21
-106.5
-341.8
-302.3
117.9
-206.57
-110.5
146
42.702
-348.0
-318.2
43.9
Ag(s)
Ag(g)
Ag*(aq)
289.2
250.4
172.892
-203
-198
57.7
(continued)
105.9
77.111
73.93
Transcribed Image Text:A-6 Appendix B • Standard Thermodynamic Values for Selected Substances Appendix B. Standard Thermodynamic Values for Selected Substances А-7 Substance AH; (kJ/mol) AG; (kJ/mol) S° Substance AH; (kJ/mol) AG; (kJ/mol) S° Substance AH; (kJ/mol) AG; (kJ/mol) S° Substance AH; (kJ/mol) AG; (kJ/mol) S° or lon (J/mol-K) or lon (J/mol-K) or lon (J/mol-K) or lon (J/mol-K) CCl,(1) COCI2(8) Cesium Cs(s) Cs(g) Cs*(g) Cs*(aq) CsF(s) CSCI(s) CsBr(s) CsI(s) -68.6 -206 -139 214.4 FeCl3(s) FeO(s) Fe,03(s) Fe;O4(s) -399.5 AgF(s) AgCl(s) AgBr(s) AgI(s) AGNO3(s) Ag,S(s) Sodium -334.1 142 155.6 -203 -185 84 HNO3(1) HNO3(aq) NF3(g) NOCI(g) NH,CI(s) Охудen O2(g) O(g) 03(8) ОН (ад) H,O(g) H2O(1) H,O2(1) H,O,(aq) Phosphorus P4(s, white) P(g) P(s, red) P2(8) PĄ(8) PCI3(8) PCI3(1) PCI5(g) PCI3(s) P,O10(s) PO (aq) НРО (ад) H,PO, (aq) H;PO4(aq) H;PO,(1) Potassium -173.23 -79.914 -220 283.74 -272.0 -251.4 -206.57 -110.5 146 -127.03 -109.72 96.11 60.75 87.400 145.3 -825.5 -743.6 -95.939 -66.32 -125 -83.3 260.6 -99.51 107.1 85.15 -1121 -1018 51.71 66.07 261.6 -62.38 114 76.7 49.7 175.5 Lead 94.6 -45.06 19.1 -40.3 -314.4 -203.0 128.2 458.5 427.1 169.72 Pb(s) Pb*(aq) PbCl2(s) PbO(s) PbO2(s) PbS(s) PbSO,(s) -31.8 146 64.785 21 -248 -282.0 133 1.6 -24.3 205.0 -554.7 -525.4 88 -359 -314 249.2 231.7 160.95 Na(s) Na(g) Na*(g) Na*(aq) NaF(s) NaCl(s) NaBr(s) NaOH(s) Na,CO3(s) NaHCO3(s) NaI(s) Strontium 136 51.446 -442.8 -395 -414 101.18 -218 -198 68.70 143 163 238.82 107.76 77.299 153.61 -383 121 -276.6 -219.0 -157.30 -228.60 76.6 -229.94 -10.54 609.839 574.877 147.85 -337 -333 130 -98.3 -96.7 91.3 -241.826 188.72 -239.66 -261.87 60.2 Chlorine -918.39 -811.24 147 -285.840 -237.192 69.940 -575.4 -545.1 51.21 Cl2(g) Cl(g) CI"(g) CI"(aq) HCI(g) HCI(aq) CIO2(g) Cl,0(g) Chromium 223.0 Lithium -187.8 -120.4 110 -411.1 -384.0 72.12 121.0 105.0 165.1 Li(s) Li(g) Li*(8) Li*(aq) LiF(s) LİCI(s) LiBr(s) LiI(s) Magnesium Mg(s) Mg(g) Mg**(g) Mg**(aq) MgCl2(s) MGCO3(s) MgO(s) Mg;N2(s) Manganese Mn(s, c) Mn*(aq) MnOg(s) MnO, (aq) Mercury Hg(1) Hg(g) Hg²*(aq) Hg*(aq) HgCl½(s) Hg,Cl,(s) HgO(s) Nitrogen N2(g) N(g) N20(g) NO(g) NO2(g) N,O3(g) N204(8) N2O5(g) N,O5(s) NH3(g) NH3(aq) N2H4(1) NO (aq) 144 -349 86.82 29.10 138.67 132.91 -191.2 -134.1 -361 -234 -240 153.25 161 128 -425.609 -379.53 64.454 -167.46 -131.17 55.10 687.163 649.989 41.1 -1130.8 -1048.1 139 -92.31 -95.30 186.79 -278.46 -293.8 14 314.6 278.3 163.1 -947.7 -851.9 102 -167.46 -131.17 55.06 -616.9 -588.7 -384 35.66 -17.6 -12.1 22.8 -288 -285 98.5 102 120 256.7 -408 59.30 144 104 218 80.3 97.9 266.1 -351 -342 Sr(s) Sr(g) Sr*(g) Sr*(aq) SrCl2(s) SrCO3(s) SrO(s) SrSO,(s) Sulfur 74.1 58.9 24.5 280 54.4 -270 -270 85.8 -287 -268 312 164 110 164.54 Cr(s) Cr**(aq) Cro (aq) Cr,O (aq) Сopper Cu(s) Cu(g) Cu*(aq) Cu²*(aq) Cu,O(s) CuO(s) Cu,S(s) CuS(s) Fluorine 23.8 -320 -272 217 1784 -1971 32.69 -402 -443.5 -2984 -323 353 -545.51 -557.3 -39 -863.2 -706.3 38 150 115 148.55 -828.4 -781.2 117 -1461 -1257 214 2351 -2698 229 -1218 -1138 97.1 -461.96 -456.01 118 -1266 -1013 -218 -592.0 -562.4 55.5 33.1 -641.6 -592.1 89.630 -1281 -1082 -36 -1445 -1334 122 341.1 301.4 166.29 -1112 -1028 65.86 26.9 -1285 -1135 89.1 51.9 64.39 50.2 -26 S(rhombic) S(monoclinic) S(g) S2(g) S8(g) s (aq) HS¯(aq) H,S(g) H,S(aq) SO2(g) SO:(8) SO (aq) HSO,(aq) H;SO,(1) H,SO4(aq) -601.2 -461 -569.0 -1277 -1019 228 31.9 64.98 -98.7 -401 88 -1271.7 -1123.6 150.8 0.3 0.096 32.6 -168.6 -146.0 93.1 279 239 168 -157.3 -130 42.63 31.8 64.672 129 80.1 228.1 K(s) K(g) K*(g) K*(aq) KF(s) KCI(s) KBr(s) KI(s) КОН(:) KCIO;(s) KCIO:(s) -79.5 -86.2 120.9 -219 -223 -84 89.2 60.7 160.23 101 49.1 430.211 -53.1 -53.6 66.5 -520.9 -466.1 53.1 514.197 481.202 154.47 41.8 83.7 22 -518.4 -425.1 190 -251.2 -282.28 103 -17.7 12.6 61.1 F2(g) F(g) F (g) F (aq) HF(g) Hydrogen H2(g) H(g) H*(aq) H*(g) 202.7 -568.6 -538.9 66.55 -20.2 -33 205.6 78.9 61.8 158.64 76.027 -436.7 -409.2 82.59 -39 -27.4 122 -255.6 -262.5 145.47 61.30 31.8 174.87 -394 -380 95.94 -296.8 -300.2 248.1 -329.1 -276.5 -9.6 171 164.4 -32 -328 -323 106.39 -396 -371 256.66 -273 -275 173.67 172 153.6 84.5 -424.8 -379.1 78.87 -907.51 -741.99 17 -230 -264.9 -885.75 -813.989 -184 144 -397.7 -296.3 143.1 -752.87 126.9 0. 130.6 -210.66 196 -432.75 -303.2 151.0 -690.059 156.90 218.0 203.30 114.60 -90.79 -58.50 70.27 Rubidium -907.51 -741.99 17 Rb(s) Rb(g) Rb*(g) Rb*(aq) RbF(s) RbCl(s) RbBr(s) RbI(s) Silicon 69.5 Tin 1536.3 1517.1 108.83 191.5 153.2 Sn(white) Sn(gray) SnCl,(1) SnO2(s) Titanium 85.81 55.86 169.99 51.5 Iodine 473 456 495.04 3 4.6 44.8 L(s) L(8) I(g) I(g) I(aq) HI(g) -116.14 82.05 104.2 219.7 -246 -282.2 124 -545.2 -474.0 259 62.442 19.38 70.21 260.58 90.29 86.60 210.65 -549.28 -580.7 -519.7 52.3 106.8 180.67 33.2 51 239.9 -435.35 -407.8 95.90 -194.7 86.6 142.4 314.7 108.3 Ti(s) TiCl,(1) TiO2(s) -389.2 -378.1 30.7 -55.94 -51.67 109.4 304.3 346 9.16 97.7 -328 -326 118.0 -804.2 -737.2 252.3 25.9 1.3 206.33 11 118 -944.0 -888.8 50.6 Iron -43.1 114 178 Zinc Si(s) SiF,(g) SiO2(s) 0. 18.0 Fe(s) Fe*(aq) Fe*(aq) FeCl2(s) 27.3 193 110 -45.9 -16 -1614.9 -1572.7 282.4 Zn(s) 41.6 -47.7 -10.5 -293 -80.83 26.7 160.9 Zn(g) Zn²*(aq) ZnO(s) ZnS(s, zinc blende) -910.9 -856.5 41.5 130.5 94.93 -87.9 -84.94 113 50.63 149.2 121.2 Silver -152.4 -147.21 -106.5 -341.8 -302.3 117.9 -206.57 -110.5 146 42.702 -348.0 -318.2 43.9 Ag(s) Ag(g) Ag*(aq) 289.2 250.4 172.892 -203 -198 57.7 (continued) 105.9 77.111 73.93
APPENDIX B
Standard Thermodynamic Values
for Selected Substances*
S°
(J/mol-K)
AH;
(kJ/mol)
AG;
(kJ/mol)
Substance
S°
AG;
(kJ/mol)
Substance
AH;
or lon
(kJ/mol)
or lon
(J/mol-K)
38.2
CaO(s)
Са(ОН), (s)
Ca3(PO4)2(s)
CASO4(s)
-635.1
-603.5
e (g)
Aluminum
20.87
-986.09
-898.56
83.39
28.3
-4138
-3899
263
Al(s)
Al*(aq)
-524.7
-481.2
-313
-1432.7
-1320.3
107
-704.2
-628.9
110.7
Carbon
AICI3(s)
Al,03(s)
50.94
5.686
C(graphite)
C(diamond)
C(g)
CO(g)
CO2(g)
CO2(aq)
CO (aq)
HCO;(aq)
H,CO;(aq)
CH4(g)
C,H¿(g)
C„H4(g)
CH6(g)
C;Hs(g)
C,H10(8)
C,H6(1)
CH;OH(g)
CH;OH(I)
НСНО(g)
HCOO¯(aq)
НСООН()
НСООН(аq)
CH;OH(g)
CH;OH(I)
CH;CHO(g)
CH;COOH(I)
C,H12O6(s)
C12H2„O|(s)
CN (aq)
HCN(g)
HCN(1)
HCN(aq)
CS-(g)
CS (1)
CH;CI(g)
CH,Cl2(1)
CHCI3(1)
CCL4(g)
-1676
-1582
Barium
1.896
2.866
2.439
62.5
715.0
669.6
158.0
Ba(s)
Ba(g)
Ba*(g)
Ba"(aq)
ВаCl(s)
BaCO3(s)
BaO(s)
BaSO,(s)
175.6
144.8
170.28
-110.5
-137.2
197.5
1649.9
-393.5
-394.4
213.7
-386.2
-528.10
-538.36
-560.7
13
-412.9
121
-806.06
-810.9
126
-676.26
-53.1
-1219
-1139
112
-691.11
587.06
95.0
-548.1
-520.4
72.07
-698.7
-623.42
191
-74.87
227
-1465
-1353
132
-50.81
186.1
Boron
209
200.85
52.47
68.36
219.22
B(B-rhombo-
hedral)
BF;(g)
BCl;(g)
B,H6(g)
B,03(s)
H;BO3(s)
Bromine
5.87
-84.667
-32.89
229.5
-1137.0
-1120.3
254.0
-105
-24.5
269.9
-403.8
-388.7
290.0
-126
-16.7
310
35
86.6
232.0
49.0
124.5
172.8
-1272
-1193
53.8
-201.2
-161.9
238
-1094.3
-969.01
88.83
-238.6
-166.2
127
-116
-110
219
152.23
-410
-335
91.6
Br2(1)
Br2(g)
Br(g)
Br (g)
Br (aq)
HBr(g)
Cadmium
-346
-356
30.91
3.13
245.38
-409
129.0
111.9
82.4
174.90
-410
164
-218.9
-235.1
-168.6
282.6
-120.9
-102.82
80.71
-277.63
-174.8
161
-36.3
-53.5
198.59
-166
-133.7
266
-487.0
-392
160
51.5
-1273.3
-910.56
212.1
Cd(s)
Cd(g)
Cd*(aq)
CdS(s)
112.8
78.2
167.64
-2221.7
-1544.3
360.24
118
201.7
-72.38
-77.74
-61.1
151
166
-144
-141
71
135
125
Calcium
105
121.
112.8
Ca(s)
41.6
105
112
129
66.9
63.6
192.6
158.9
154.78
117
237.79
Ca(g)
Ca*(g)
Ca*(aq)
CaF2(s)
CaCl2(s)
CACO3(s)
1934.1
87.9
151.0
-542.96
-553.04
-55.2
-83.7
-60.2
234
-1215
-1162
68.87
-117
-63.2
179
-795.0
-750.2
114
-132
-71.5
203
-1206.9
-1128.8
92.9
-96.0
-53.7
309.7
*All values at 298 K.
(сontinued)
A-5
Transcribed Image Text:APPENDIX B Standard Thermodynamic Values for Selected Substances* S° (J/mol-K) AH; (kJ/mol) AG; (kJ/mol) Substance S° AG; (kJ/mol) Substance AH; or lon (kJ/mol) or lon (J/mol-K) 38.2 CaO(s) Са(ОН), (s) Ca3(PO4)2(s) CASO4(s) -635.1 -603.5 e (g) Aluminum 20.87 -986.09 -898.56 83.39 28.3 -4138 -3899 263 Al(s) Al*(aq) -524.7 -481.2 -313 -1432.7 -1320.3 107 -704.2 -628.9 110.7 Carbon AICI3(s) Al,03(s) 50.94 5.686 C(graphite) C(diamond) C(g) CO(g) CO2(g) CO2(aq) CO (aq) HCO;(aq) H,CO;(aq) CH4(g) C,H¿(g) C„H4(g) CH6(g) C;Hs(g) C,H10(8) C,H6(1) CH;OH(g) CH;OH(I) НСНО(g) HCOO¯(aq) НСООН() НСООН(аq) CH;OH(g) CH;OH(I) CH;CHO(g) CH;COOH(I) C,H12O6(s) C12H2„O|(s) CN (aq) HCN(g) HCN(1) HCN(aq) CS-(g) CS (1) CH;CI(g) CH,Cl2(1) CHCI3(1) CCL4(g) -1676 -1582 Barium 1.896 2.866 2.439 62.5 715.0 669.6 158.0 Ba(s) Ba(g) Ba*(g) Ba"(aq) ВаCl(s) BaCO3(s) BaO(s) BaSO,(s) 175.6 144.8 170.28 -110.5 -137.2 197.5 1649.9 -393.5 -394.4 213.7 -386.2 -528.10 -538.36 -560.7 13 -412.9 121 -806.06 -810.9 126 -676.26 -53.1 -1219 -1139 112 -691.11 587.06 95.0 -548.1 -520.4 72.07 -698.7 -623.42 191 -74.87 227 -1465 -1353 132 -50.81 186.1 Boron 209 200.85 52.47 68.36 219.22 B(B-rhombo- hedral) BF;(g) BCl;(g) B,H6(g) B,03(s) H;BO3(s) Bromine 5.87 -84.667 -32.89 229.5 -1137.0 -1120.3 254.0 -105 -24.5 269.9 -403.8 -388.7 290.0 -126 -16.7 310 35 86.6 232.0 49.0 124.5 172.8 -1272 -1193 53.8 -201.2 -161.9 238 -1094.3 -969.01 88.83 -238.6 -166.2 127 -116 -110 219 152.23 -410 -335 91.6 Br2(1) Br2(g) Br(g) Br (g) Br (aq) HBr(g) Cadmium -346 -356 30.91 3.13 245.38 -409 129.0 111.9 82.4 174.90 -410 164 -218.9 -235.1 -168.6 282.6 -120.9 -102.82 80.71 -277.63 -174.8 161 -36.3 -53.5 198.59 -166 -133.7 266 -487.0 -392 160 51.5 -1273.3 -910.56 212.1 Cd(s) Cd(g) Cd*(aq) CdS(s) 112.8 78.2 167.64 -2221.7 -1544.3 360.24 118 201.7 -72.38 -77.74 -61.1 151 166 -144 -141 71 135 125 Calcium 105 121. 112.8 Ca(s) 41.6 105 112 129 66.9 63.6 192.6 158.9 154.78 117 237.79 Ca(g) Ca*(g) Ca*(aq) CaF2(s) CaCl2(s) CACO3(s) 1934.1 87.9 151.0 -542.96 -553.04 -55.2 -83.7 -60.2 234 -1215 -1162 68.87 -117 -63.2 179 -795.0 -750.2 114 -132 -71.5 203 -1206.9 -1128.8 92.9 -96.0 -53.7 309.7 *All values at 298 K. (сontinued) A-5
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