% Transmittance ° 20 40 60 80 100 % Transmittance 8 60 80 100 20 Reactant-acetanilide 4000 3600 3000 2500 2000 1500 1000 Wavenumber (cm) Product: 4-bromoacetanilide 4000 3500 3000 2500 Wavenumber (cm) 2000 1500 1000 Both the reactant and product show very similar IR spectra. For the reactant, indicate which IR signals are due to the presence of the amide group? Specifically, which signal is due the NH stretch (indicate which signal is due to the "free" NH stretching vibration and which signal is due to the "hydrogen bonded" NH stretching vibration? You may either type your answers below, or write your answers on the given spectrum shown above. NH bond (Hydrogen bonded) • NH bond ("free") Carbonyl bond

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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With reference to the provided IR spectra, answer the following questions.

% Transmittance
°
20
40
60
80
100
% Transmittance
8
60
80
100
20
Reactant-acetanilide
4000
3600
3000
2500
2000
1500
1000
Wavenumber (cm)
Product: 4-bromoacetanilide
4000
3500
3000
2500
Wavenumber (cm)
2000
1500
1000
Transcribed Image Text:% Transmittance ° 20 40 60 80 100 % Transmittance 8 60 80 100 20 Reactant-acetanilide 4000 3600 3000 2500 2000 1500 1000 Wavenumber (cm) Product: 4-bromoacetanilide 4000 3500 3000 2500 Wavenumber (cm) 2000 1500 1000
Both the reactant and product show very similar IR spectra. For the reactant, indicate which IR
signals are due to the presence of the amide group? Specifically, which signal is due the NH
stretch (indicate which signal is due to the "free" NH stretching vibration and which signal is due
to the "hydrogen bonded" NH stretching vibration?
You may either type your answers below, or write your answers on the given spectrum
shown above.
NH bond (Hydrogen bonded)
• NH bond ("free")
Carbonyl bond
Transcribed Image Text:Both the reactant and product show very similar IR spectra. For the reactant, indicate which IR signals are due to the presence of the amide group? Specifically, which signal is due the NH stretch (indicate which signal is due to the "free" NH stretching vibration and which signal is due to the "hydrogen bonded" NH stretching vibration? You may either type your answers below, or write your answers on the given spectrum shown above. NH bond (Hydrogen bonded) • NH bond ("free") Carbonyl bond
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