Part B - Measuring Electrode Potentials From your results, arrange these reductions in order of decreasing reduction potential: 1. Get a sample tube and a piece of metal for each of the half-cells listed on the right. Also get one pre-assembled copper half-cell (as shown in the photo on the left below). Half-Cells Zn2*(aq) + Pb2*(aq) + Sn2*(aq) + Cu2"(aq) + 2e Zn(s) Zn2+| Zn 2e Pb(s) -> 2e Sn(s) Cu(s) 2. Half fill cach sample tube with the 1 M solution of the appropriate metal cation. Pb2+| Pb Sn2+ | Sn 2e 3. Insert a two holed plastic cap into cach tube and insert the piece of clean metal (Zn, Pb, or Sn) appropriate to the cell into one hole. Each group should have a set of cells as pictured on the right below. From ALL the species listed above (metals and metal ions), select: Provide a brief justification for your choice of best oxidant and best reductant. Pb Sn Zn 2/ Sn²/ Given that the standard reduction potential for Fe (Fe2*(aq) + 2e -→ Fe(s)) is -0.44 v, would any of the metals zinc, lead, or tin, be effective as a sacrificial anode to inhibit the corrosion of iron? Justify your answer and also indicate if this agrees 4. Starting with the Zn²* | Zn half-cell, insert the copper half-cell into the second hole in the plastic cap (as shown in the picture below). Make sure the bottom of the copper half-cell dips well into the solution in the tube. with your observations from part A. Pb Sn Sn2 /9 Attach the lead from the VOA terminal of the multimeter to the Cu clectrode and the other lead (from the COM terminal on the voltmeter) to the other metal in the cell. Record the voltage produced by the cell. Determine whether the Cu half- cell is the positive or negative electrode. The multimeter shows a positive reading if the electrode connected to the VNA terminal is positive with respect to the electrode connected to the COM terminal. Since you have connected the copper electrode to the VQA terminal, a positive reading tells you that the copper electrode is the more positive of the two clectrodes in the cell. Disconnect the multimeter from the cell when you have completed your reading. Make sure you determine the cell voltage and whether the copper half-cell is the more positive before you disassemble the cell. 5. Repeat step 4 for the Pb2+ | Pb and the Sn2+ | Sn half-cells. 6. Disassemble the cells and discard the metal solutions into the heavy metals waste container. Rinse the equipment, including the metals, before returning them to where you got them.
Part B - Measuring Electrode Potentials From your results, arrange these reductions in order of decreasing reduction potential: 1. Get a sample tube and a piece of metal for each of the half-cells listed on the right. Also get one pre-assembled copper half-cell (as shown in the photo on the left below). Half-Cells Zn2*(aq) + Pb2*(aq) + Sn2*(aq) + Cu2"(aq) + 2e Zn(s) Zn2+| Zn 2e Pb(s) -> 2e Sn(s) Cu(s) 2. Half fill cach sample tube with the 1 M solution of the appropriate metal cation. Pb2+| Pb Sn2+ | Sn 2e 3. Insert a two holed plastic cap into cach tube and insert the piece of clean metal (Zn, Pb, or Sn) appropriate to the cell into one hole. Each group should have a set of cells as pictured on the right below. From ALL the species listed above (metals and metal ions), select: Provide a brief justification for your choice of best oxidant and best reductant. Pb Sn Zn 2/ Sn²/ Given that the standard reduction potential for Fe (Fe2*(aq) + 2e -→ Fe(s)) is -0.44 v, would any of the metals zinc, lead, or tin, be effective as a sacrificial anode to inhibit the corrosion of iron? Justify your answer and also indicate if this agrees 4. Starting with the Zn²* | Zn half-cell, insert the copper half-cell into the second hole in the plastic cap (as shown in the picture below). Make sure the bottom of the copper half-cell dips well into the solution in the tube. with your observations from part A. Pb Sn Sn2 /9 Attach the lead from the VOA terminal of the multimeter to the Cu clectrode and the other lead (from the COM terminal on the voltmeter) to the other metal in the cell. Record the voltage produced by the cell. Determine whether the Cu half- cell is the positive or negative electrode. The multimeter shows a positive reading if the electrode connected to the VNA terminal is positive with respect to the electrode connected to the COM terminal. Since you have connected the copper electrode to the VQA terminal, a positive reading tells you that the copper electrode is the more positive of the two clectrodes in the cell. Disconnect the multimeter from the cell when you have completed your reading. Make sure you determine the cell voltage and whether the copper half-cell is the more positive before you disassemble the cell. 5. Repeat step 4 for the Pb2+ | Pb and the Sn2+ | Sn half-cells. 6. Disassemble the cells and discard the metal solutions into the heavy metals waste container. Rinse the equipment, including the metals, before returning them to where you got them.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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