Part B - Measuring Electrode Potentials From your results, arrange these reductions in order of decreasing reduction potential: 1. Get a sample tube and a piece of metal for each of the half-cells listed on the right. Also get one pre-assembled copper half-cell (as shown in the photo on the left below). Half-Cells Zn2*(aq) + Pb2*(aq) + Sn2*(aq) + Cu2"(aq) + 2e Zn(s) Zn2+| Zn 2e Pb(s) -> 2e Sn(s) Cu(s) 2. Half fill cach sample tube with the 1 M solution of the appropriate metal cation. Pb2+| Pb Sn2+ | Sn 2e 3. Insert a two holed plastic cap into cach tube and insert the piece of clean metal (Zn, Pb, or Sn) appropriate to the cell into one hole. Each group should have a set of cells as pictured on the right below. From ALL the species listed above (metals and metal ions), select: Provide a brief justification for your choice of best oxidant and best reductant. Pb Sn Zn 2/ Sn²/ Given that the standard reduction potential for Fe (Fe2*(aq) + 2e -→ Fe(s)) is -0.44 v, would any of the metals zinc, lead, or tin, be effective as a sacrificial anode to inhibit the corrosion of iron? Justify your answer and also indicate if this agrees 4. Starting with the Zn²* | Zn half-cell, insert the copper half-cell into the second hole in the plastic cap (as shown in the picture below). Make sure the bottom of the copper half-cell dips well into the solution in the tube. with your observations from part A. Pb Sn Sn2 /9 Attach the lead from the VOA terminal of the multimeter to the Cu clectrode and the other lead (from the COM terminal on the voltmeter) to the other metal in the cell. Record the voltage produced by the cell. Determine whether the Cu half- cell is the positive or negative electrode. The multimeter shows a positive reading if the electrode connected to the VNA terminal is positive with respect to the electrode connected to the COM terminal. Since you have connected the copper electrode to the VQA terminal, a positive reading tells you that the copper electrode is the more positive of the two clectrodes in the cell. Disconnect the multimeter from the cell when you have completed your reading. Make sure you determine the cell voltage and whether the copper half-cell is the more positive before you disassemble the cell. 5. Repeat step 4 for the Pb2+ | Pb and the Sn2+ | Sn half-cells. 6. Disassemble the cells and discard the metal solutions into the heavy metals waste container. Rinse the equipment, including the metals, before returning them to where you got them.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Part B – Measuring Electrode Potentials
From your results, arrange these reductions in order of decreasing reduction potential:
1.
Get a sample tube and a piece of metal for each of the half-cells listed on the right. Also
get one pre-assembled copper half-cell (as shown in the photo on the left below).
Half-Cells
Zn2+(aq) +
Pb2*(aq) +
Sn2*(aq) +
Cu2*(aq) +
2e
Zn(s)
Zn2+ | Zn
2e
Pb(s)
2.
Half fill each sample tube with the 1 M solution of the appropriate metal cation.
2e
Sn(s)
Pb2+ | Pb
Sn2+ | Sn
2e
Cu(s)
3.
Insert a two holed plastic cap into each tube and insert the piece of clean metal (Zn, Pb,
or Sn) appropriate to the cell into one hole. Each group should have a set of cells as
pictured on the right below.
From ALL the species listed above (metals and metal ions), select:
Provide a brief justification for your choice of best oxidant and best reductant.
Pb
Sn
Sn2/
Zn2+/
Given that the standard reduction potential for Fe (Fe2+(aq) + 2e→ Fe(s)) is -0.44 V, would any of the metals zinc, lead,
or tin, be effective as a sacrificial anode to inhibit the corrosion of iron? Justify your answer and also indicate if this agrees
4.
Starting with the Zn2+ | Zn half-cell, insert the copper half-cell into the second hole in the plastic cap (as shown in the
with your observations from part A.
picture below). Make sure the bottom of the copper half-cell dips well into the solution in the tube.
Pb
Sn
Attach the lead from the VQA terminal of the multimeter to the Cu electrode and the other lead (from the COM terminal
on the voltmeter) to the other metal in the cell. Record the voltage produced by the cell. Determine whether the Cu half-
cell is the positive or negative electrode. The multimeter shows a positive reading if the electrode connected to the VNA
terminal is positive with respect to the electrode connected to the COM terminal. Since you have connected the copper
electrode to the VQA terminal, a positive reading tells you that the copper electrode is the more positive of the two
electrodes in the cell. Disconnect the multimeter from the cell when you have completed your reading.
Make sure you determine the cell voltage and whether the copper half-cell is the more positive before you disassemble
the cell.
5.
Repeat step 4 for the Pb2+ | Pb and the Sn2+ | Sn half-cells.
6.
Disassemble the cells and discard the metal solutions into the heavy metals waste container. Rinse the equipment,
including the metals, before returning them to where you got them.
Transcribed Image Text:Part B – Measuring Electrode Potentials From your results, arrange these reductions in order of decreasing reduction potential: 1. Get a sample tube and a piece of metal for each of the half-cells listed on the right. Also get one pre-assembled copper half-cell (as shown in the photo on the left below). Half-Cells Zn2+(aq) + Pb2*(aq) + Sn2*(aq) + Cu2*(aq) + 2e Zn(s) Zn2+ | Zn 2e Pb(s) 2. Half fill each sample tube with the 1 M solution of the appropriate metal cation. 2e Sn(s) Pb2+ | Pb Sn2+ | Sn 2e Cu(s) 3. Insert a two holed plastic cap into each tube and insert the piece of clean metal (Zn, Pb, or Sn) appropriate to the cell into one hole. Each group should have a set of cells as pictured on the right below. From ALL the species listed above (metals and metal ions), select: Provide a brief justification for your choice of best oxidant and best reductant. Pb Sn Sn2/ Zn2+/ Given that the standard reduction potential for Fe (Fe2+(aq) + 2e→ Fe(s)) is -0.44 V, would any of the metals zinc, lead, or tin, be effective as a sacrificial anode to inhibit the corrosion of iron? Justify your answer and also indicate if this agrees 4. Starting with the Zn2+ | Zn half-cell, insert the copper half-cell into the second hole in the plastic cap (as shown in the with your observations from part A. picture below). Make sure the bottom of the copper half-cell dips well into the solution in the tube. Pb Sn Attach the lead from the VQA terminal of the multimeter to the Cu electrode and the other lead (from the COM terminal on the voltmeter) to the other metal in the cell. Record the voltage produced by the cell. Determine whether the Cu half- cell is the positive or negative electrode. The multimeter shows a positive reading if the electrode connected to the VNA terminal is positive with respect to the electrode connected to the COM terminal. Since you have connected the copper electrode to the VQA terminal, a positive reading tells you that the copper electrode is the more positive of the two electrodes in the cell. Disconnect the multimeter from the cell when you have completed your reading. Make sure you determine the cell voltage and whether the copper half-cell is the more positive before you disassemble the cell. 5. Repeat step 4 for the Pb2+ | Pb and the Sn2+ | Sn half-cells. 6. Disassemble the cells and discard the metal solutions into the heavy metals waste container. Rinse the equipment, including the metals, before returning them to where you got them.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 3 images

Blurred answer
Knowledge Booster
Electrochemical Cells
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY