Part A Rank these systems in order of decreasing entropy. Rank from highest to lowest entropy. To rank items as equivalent, overlap them. Reset Help 1 mol of helium gas at 273 K and 20 L 1 mol of carbon disulfide gas at 273 K and 40 L 1 mol of helium gas at 273 K and 40 L 1 mol of nitrogen gas at |273 K and 40 L 1/2 mol of 1/2 mol of 1/2 mol of helium gas at 100 K and 20 L liquid helium at 100 K helium gas at 273 K and 20 L Greatest entropy Least entropy O The correct ranking cannot be determined.

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Chapter1: Chemical Foundations
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Entropy is the randomness of a system. At the molecular level, entropy can be described in terms of the possible number of different arrangements of particle positions and energies, called microstates. The more microstates the system has, the greater its entropy.
Microstates depend on molecular motion. Molecules may undergo three different types of motion: translational motion, vibrational motion, and rotational motion. During translational motion, the entire molecule moves in one direction. During vibrational motion, atoms in a molecule move toward and away from one another. During rotational motion, molecules rotate or spin. The number of
molecules, the space available for the molecules, and the energy available to the molecules will impact the number of microstates.
Another way of looking at entropy is that the universe is moving toward a broader distribution of energy. The universe has a constant amount of energy as stated in the first law of thermodynamics. The universe started with low entropy (concentrated in the moment before the "big bang") and the entropy has since been constantly increasing by distributing this energy. Heat distribution from high
temperature to low temperature is a another example of this phenomenon.
Transcribed Image Text:Entropy is the randomness of a system. At the molecular level, entropy can be described in terms of the possible number of different arrangements of particle positions and energies, called microstates. The more microstates the system has, the greater its entropy. Microstates depend on molecular motion. Molecules may undergo three different types of motion: translational motion, vibrational motion, and rotational motion. During translational motion, the entire molecule moves in one direction. During vibrational motion, atoms in a molecule move toward and away from one another. During rotational motion, molecules rotate or spin. The number of molecules, the space available for the molecules, and the energy available to the molecules will impact the number of microstates. Another way of looking at entropy is that the universe is moving toward a broader distribution of energy. The universe has a constant amount of energy as stated in the first law of thermodynamics. The universe started with low entropy (concentrated in the moment before the "big bang") and the entropy has since been constantly increasing by distributing this energy. Heat distribution from high temperature to low temperature is a another example of this phenomenon.
Part A
Rank these systems in order of decreasing entropy.
Rank from highest to lowest entropy. To rank items as equivalent, overlap them.
Reset Help
1 mol of
helium gas at
| 273 K and 20 L
1 mol of
carbon disulfide gas at
273 K and 40 L
1/2 mol of
liquid helium
at 100 K
1 mol of
helium gas at
273 K and 40 L
1 mol of
nitrogen gas at
273 K and 40 L
1/2 mol of
1/2 mol of
helium gas at
273 K and 20 L
helium gas at
100 K and 20 L
Greatest entropy
Least entropy
O The correct ranking cannot be determined.
Transcribed Image Text:Part A Rank these systems in order of decreasing entropy. Rank from highest to lowest entropy. To rank items as equivalent, overlap them. Reset Help 1 mol of helium gas at | 273 K and 20 L 1 mol of carbon disulfide gas at 273 K and 40 L 1/2 mol of liquid helium at 100 K 1 mol of helium gas at 273 K and 40 L 1 mol of nitrogen gas at 273 K and 40 L 1/2 mol of 1/2 mol of helium gas at 273 K and 20 L helium gas at 100 K and 20 L Greatest entropy Least entropy O The correct ranking cannot be determined.
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