▾ Part A For the following systems at equilibrium A: 2NOCI(g) B: H₂(g) + I2(g) = 2HI(g) classify these changes by their effect. Drag the appropriate items to their respective bins. ▸ View Available Hint(s) System A Increase container size 2NO(g) + Cl₂ (g) Leftward shift System A Decrease container size System B Decrease container size No shift Reset Help System B Increase container size Rightward shift

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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**Le Châtelier's Principle and System Shifts in Equilibrium Reactions**

**Introduction:**
According to Le Châtelier's principle, a system at equilibrium will respond to a stress by shifting in the direction that relieves the stress. This principle explains how chemical reactions can be shifted from their equilibrium positions by changing the volume, temperature, or by adding/removing reactants or products.

**Part A:**

**For the following systems at equilibrium:**

1. **System A:**
   \[ 2\text{NOCl}(g) \rightleftharpoons 2\text{NO}(g) + \text{Cl}_2(g) \]

**Effect of Changing Container Size:**
- **Increase container size:** 
- **Decrease container size:** 

**System B:**
   \[ \text{H}_2(g) + \text{I}_2(g) \rightleftharpoons 2\text{HI}(g) \]

**Effect of Changing Container Size:**
- **Increase container size:** 
- **Decrease container size:** 

**Classify these changes by their effect:**
- **Leftward shift**
- **No shift**
- **Rightward shift**

*Interactive Diagram:*
There is an interactive element where learners can drag the options under each system to bins labeled "Leftward shift," "No shift," or "Rightward shift."

**Part B:**

**For the following systems at equilibrium:**

1. **System C:**
   \[ \text{CaCO}_3(s) \rightleftharpoons \text{CaO}(s) + \text{CO}_2(g) \quad \Delta H = +178 \, \text{kJ/mol} \]

2. **System D:**
   \[ \text{PCl}_5(g) \rightleftharpoons \text{PCl}_3(g) + \text{Cl}_2(g) \quad \Delta H = -88 \, \text{kJ/mol} \]

**Effect of Changing Temperature:**
- **System C:**
  - Increase temperature
  - Decrease temperature

- **System D:**
  - Increase temperature
  - Decrease temperature

**Classify these changes by their effect:**
- **Leftward shift**
- **No shift**
- **Rightward shift**

*Interactive Diagram:*
This section
Transcribed Image Text:**Le Châtelier's Principle and System Shifts in Equilibrium Reactions** **Introduction:** According to Le Châtelier's principle, a system at equilibrium will respond to a stress by shifting in the direction that relieves the stress. This principle explains how chemical reactions can be shifted from their equilibrium positions by changing the volume, temperature, or by adding/removing reactants or products. **Part A:** **For the following systems at equilibrium:** 1. **System A:** \[ 2\text{NOCl}(g) \rightleftharpoons 2\text{NO}(g) + \text{Cl}_2(g) \] **Effect of Changing Container Size:** - **Increase container size:** - **Decrease container size:** **System B:** \[ \text{H}_2(g) + \text{I}_2(g) \rightleftharpoons 2\text{HI}(g) \] **Effect of Changing Container Size:** - **Increase container size:** - **Decrease container size:** **Classify these changes by their effect:** - **Leftward shift** - **No shift** - **Rightward shift** *Interactive Diagram:* There is an interactive element where learners can drag the options under each system to bins labeled "Leftward shift," "No shift," or "Rightward shift." **Part B:** **For the following systems at equilibrium:** 1. **System C:** \[ \text{CaCO}_3(s) \rightleftharpoons \text{CaO}(s) + \text{CO}_2(g) \quad \Delta H = +178 \, \text{kJ/mol} \] 2. **System D:** \[ \text{PCl}_5(g) \rightleftharpoons \text{PCl}_3(g) + \text{Cl}_2(g) \quad \Delta H = -88 \, \text{kJ/mol} \] **Effect of Changing Temperature:** - **System C:** - Increase temperature - Decrease temperature - **System D:** - Increase temperature - Decrease temperature **Classify these changes by their effect:** - **Leftward shift** - **No shift** - **Rightward shift** *Interactive Diagram:* This section
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