Part A-2. Calculation for the Concentrations of the Given Solutions Fill out the table below and determine the concentration of FeSCN2+ in each sample. Remember for Part A the limiting reactant is SCN (Calculations, Table 1: Concentration of Solutions and Absorbance Values Show sample Moles of Moles of Concentration of calculation below Beaker SCN FESCN2+ FESCN2+ (M) 1 4 Insert your ALL calculations here:

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Please calculate the 4 concentrations of the FeScN3 in part A2 and fill out the table, show all work.

**Part A-2. Calculation for the Concentrations of the Given Solutions**

Fill out the table below and determine the concentration of FeSCN²⁺ in each sample. Remember for Part A, the limiting reactant is SCN⁻.

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**Table 1: Concentration of Solutions and Absorbance Values**

| Beaker | Moles of SCN⁻ | Moles of FeSCN²⁺ | Concentration of FeSCN²⁺ (M) |
|--------|--------------|------------------|-----------------------------|
|   1    |              |                  |                             |
|   2    |              |                  |                             |
|   3    |              |                  |                             |
|   4    |              |                  |                             |

*Show sample calculation below.*

---

**Insert your ALL calculations here:**
Transcribed Image Text:**Part A-2. Calculation for the Concentrations of the Given Solutions** Fill out the table below and determine the concentration of FeSCN²⁺ in each sample. Remember for Part A, the limiting reactant is SCN⁻. --- **Table 1: Concentration of Solutions and Absorbance Values** | Beaker | Moles of SCN⁻ | Moles of FeSCN²⁺ | Concentration of FeSCN²⁺ (M) | |--------|--------------|------------------|-----------------------------| | 1 | | | | | 2 | | | | | 3 | | | | | 4 | | | | *Show sample calculation below.* --- **Insert your ALL calculations here:**
**I. Objective:**

To determine the equilibrium constant for the formation of a complex ion, FeSCN²⁺.

\[ \text{Fe}^{3+} \, (aq) + \text{SCN}^- \, (aq) \leftrightarrow \text{FeSCN}^{2+} \, (aq) \]

\[ K_f = \frac{[\text{FeSCN}^{2+}]}{[\text{Fe}^{3+}][\text{SCN}^-]} \]

**II. Observations:**

**Part A. Constructing a Beer’s Law Plot**

Five solutions are prepared according to the table below. We assume in this first part, that the SCN⁻ determines the concentration of FeSCN²⁺ formed (because Fe³⁺ is in excess and SCN⁻ is limiting). So we can calculate the FeSCN²⁺ concentration just by using the moles of SCN⁻ that we started with.

**Data Table 1.**

| Beaker Number | 0.200 M Fe(NO)₃ (mL) | 0.0020 M KSCN (mL) | H₂O (mL) |
|---------------|----------------------|--------------------|----------|
| 1             | 5.0                  | 5.0                | 40.0     |
| 2             | 5.0                  | 4.0                | 41.0     |
| 3             | 5.0                  | 3.0                | 42.0     |
| 4             | 5.0                  | 2.0                | 43.0     |
| 5 (Blank)     | Data not needed      | Data not needed    | Data not needed |

The samples are run on a visible spectrometer and an **example** of the data is shown below.

**Graph Explanation:**

The graph titled "Visible Spectra for 4 FeSCN²⁺ solutions" displays the absorbance on the y-axis and the wavelength (nm) on the x-axis. There are four curves, each representing a different FeSCN²⁺ solution concentration. The x-axis ranges from 400 nm to 600 nm, and absorbance is measured from 0 to 1.2. The curves typically show a peak in
Transcribed Image Text:**I. Objective:** To determine the equilibrium constant for the formation of a complex ion, FeSCN²⁺. \[ \text{Fe}^{3+} \, (aq) + \text{SCN}^- \, (aq) \leftrightarrow \text{FeSCN}^{2+} \, (aq) \] \[ K_f = \frac{[\text{FeSCN}^{2+}]}{[\text{Fe}^{3+}][\text{SCN}^-]} \] **II. Observations:** **Part A. Constructing a Beer’s Law Plot** Five solutions are prepared according to the table below. We assume in this first part, that the SCN⁻ determines the concentration of FeSCN²⁺ formed (because Fe³⁺ is in excess and SCN⁻ is limiting). So we can calculate the FeSCN²⁺ concentration just by using the moles of SCN⁻ that we started with. **Data Table 1.** | Beaker Number | 0.200 M Fe(NO)₃ (mL) | 0.0020 M KSCN (mL) | H₂O (mL) | |---------------|----------------------|--------------------|----------| | 1 | 5.0 | 5.0 | 40.0 | | 2 | 5.0 | 4.0 | 41.0 | | 3 | 5.0 | 3.0 | 42.0 | | 4 | 5.0 | 2.0 | 43.0 | | 5 (Blank) | Data not needed | Data not needed | Data not needed | The samples are run on a visible spectrometer and an **example** of the data is shown below. **Graph Explanation:** The graph titled "Visible Spectra for 4 FeSCN²⁺ solutions" displays the absorbance on the y-axis and the wavelength (nm) on the x-axis. There are four curves, each representing a different FeSCN²⁺ solution concentration. The x-axis ranges from 400 nm to 600 nm, and absorbance is measured from 0 to 1.2. The curves typically show a peak in
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