Page < > of 10 d) In the 'HNMR spectrum below, write the product of the coupling reaction and assign the various resonances to the hydrogen nuclei responsible for them. CH3- - CH,OH CHC, 7.7 7.6 7.5 7.4 7.3 72 ppm TMS 10 &, ppm (a) 'H NMR spectrum (300 MHz). (b) "C NMR data: 8 21.3, 65.4, 127.1, 127.3, 127.7, 129.7, 137.3, 138.1, 139.8, 140.8.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Page <
9.
>
of 10
ZOOM
+
d) In the 'HNMR spectrum below, write the product of the coupling reaction and assign
the various resonances to the hydrogen nuclei responsible for them.
CH3
- CH,OH
CHCI,
77
7.6
7.5
7.4
7.3
7.2 ppm
TMS
10
9
4
1
8, ppm
(a) 'H NMR spectrum (300 MHz).
(b) C NMR data: 8 21.3, 65.4, 127.1, 127.3, 127.7, 129.7, 137.3, 138.1, 139.8, 140.8.
Transcribed Image Text:Page < 9. > of 10 ZOOM + d) In the 'HNMR spectrum below, write the product of the coupling reaction and assign the various resonances to the hydrogen nuclei responsible for them. CH3 - CH,OH CHCI, 77 7.6 7.5 7.4 7.3 7.2 ppm TMS 10 9 4 1 8, ppm (a) 'H NMR spectrum (300 MHz). (b) C NMR data: 8 21.3, 65.4, 127.1, 127.3, 127.7, 129.7, 137.3, 138.1, 139.8, 140.8.
Page <
9.
>
of 10
ZOOM
+
c) In the 'HNMR spectrum for 4-methylphenylboronic acid, assign the various
resonances to the hydrogen nuclei responsible for them.
8
CH3
B(OH)2
8.2 8.0 7.8 7.6 7.4 7.2 ppm
CHCI,
TMS
10
9
8
7
6
4
3
1
8, ppm
(a) 'H NMR spectrum (300 MHz).
(b) 1°C NMR data: 8 22.1, 129.0, 135.9, 143.1 (signal for carbon atom bound to
boron not detected).
Transcribed Image Text:Page < 9. > of 10 ZOOM + c) In the 'HNMR spectrum for 4-methylphenylboronic acid, assign the various resonances to the hydrogen nuclei responsible for them. 8 CH3 B(OH)2 8.2 8.0 7.8 7.6 7.4 7.2 ppm CHCI, TMS 10 9 8 7 6 4 3 1 8, ppm (a) 'H NMR spectrum (300 MHz). (b) 1°C NMR data: 8 22.1, 129.0, 135.9, 143.1 (signal for carbon atom bound to boron not detected).
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