P18A.2 Nitrogen dioxide reacts bimolecularly in the gas phase according to NO, + NO, → NO + NO + O,. The temperature dependence of the second- order rate constant for the rate law d[P]/dt = k,[NO,J² is given below. What are the steric factor and the reactive cross-section for the reaction? T/K 600 700 800 1000 k/(cm°mol"s") 4.6 x 10? 9.7 x 10 1.3 x 10 3.1 x 106 Take o = 0.60 nm?.

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P18A.2 Nitrogen dioxide reacts bimolecularly in the gas phase according to
NO, + NO, → NO + NO + O,. The temperature dependence of the second-
order rate constant for the rate law d[P]/dt = k,[NO,J² is given below. What
are the steric factor and the reactive cross-section for the reaction?
T/K
600
700
800
1000
k/(cm°mol"s")
4.6 x 10?
9.7 x 10
1.3 x 10
3.1 x 106
Take o = 0.60 nm?.
Transcribed Image Text:P18A.2 Nitrogen dioxide reacts bimolecularly in the gas phase according to NO, + NO, → NO + NO + O,. The temperature dependence of the second- order rate constant for the rate law d[P]/dt = k,[NO,J² is given below. What are the steric factor and the reactive cross-section for the reaction? T/K 600 700 800 1000 k/(cm°mol"s") 4.6 x 10? 9.7 x 10 1.3 x 10 3.1 x 106 Take o = 0.60 nm?.
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