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P11B.10 The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written F(J,K)= BJ(J+1)+(Ã-B)K²- Ď,J³(J+1)°–ϵJ(J+1)K²-Ď«K* (a) Develop an expression for the wavenumbers of the allowed rotational transitions. (b) The following transition frequencies (in gigahertz, GHz) were observed for CH,F: 51.0718 102.1426 102.1408 153.2103 153.2076 Evaluate as many constants in the expression for the rotational terms as these values permit.

P11B.10 The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written F(J,K)= BJ(J+1)+(Ã-B)K²- Ď,J³(J+1)°–ϵJ(J+1)K²-Ď«K* (a) Develop an expression for the wavenumbers of the allowed rotational transitions. (b) The following transition frequencies (in gigahertz, GHz) were observed for CH,F: 51.0718 102.1426 102.1408 153.2103 153.2076 Evaluate as many constants in the expression for the rotational terms as these values permit.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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P11B.10 The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written F(J,K)= BJ(J+1)+(Ã-B)K²- Ď,J³(J+1)°–ϵJ(J+1)K²-Ď«K* (a) Develop an expression for the wavenumbers of the allowed rotational transitions. (b) The following transition frequencies (in gigahertz, GHz) were observed for CH,F: 51.0718 102.1426 102.1408 153.2103 153.2076 Evaluate as many constants in the expression for the rotational terms as these values permit.
Transcribed Image Text:P11B.10 The rotational terms of a symmetric top, allowing for centrifugal distortion, are commonly written F(J,K)= BJ(J+1)+(Ã-B)K²- Ď,J³(J+1)°–ϵJ(J+1)K²-Ď«K* (a) Develop an expression for the wavenumbers of the allowed rotational transitions. (b) The following transition frequencies (in gigahertz, GHz) were observed for CH,F: 51.0718 102.1426 102.1408 153.2103 153.2076 Evaluate as many constants in the expression for the rotational terms as these values permit.
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