p. q. r. S. t. Cl₂ (excess) Br₂ 1. NaNH2 2. CH3 Br Cl₂ (excess) 1. NaNH2 2. Br

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Chemical Reaction Problems

#### Problem p.
- **Reactant**: A linear alkyne compound
- **Reagent**: \( \text{Cl}_2 \, (\text{excess}) \)
- **Description**: The alkyne undergoes halogenation with excess chlorine.

#### Problem q.
- **Reactant**: A branched alkyne
- **Reagent**: \( \text{Br}_2 \)
- **Description**: The alkyne is treated with bromine for halogenation.

#### Problem r.
- **Reactant**: An internal alkyne
- **Reagents**: 
  1. \( \text{NaNH}_2 \)
  2. \( \text{CH}_3\text{Br} \)
- **Description**: The alkyne undergoes deprotonation with sodium amide, followed by alkylation using methyl bromide.

#### Problem s.
- **Reactant**: A branched alkyne
- **Reagent**: \( \text{Cl}_2 \, (\text{excess}) \)
- **Description**: Halogenation of the alkyne using an excess of chlorine.

#### Problem t.
- **Reactant**: A linear alkyne
- **Reagents**: 
  1. \( \text{NaNH}_2 \)
  2. \( \text{BrCH}_2CH_3 \)
- **Description**: The alkyne is first treated with sodium amide for deprotonation, followed by alkylation using bromoethane.
Transcribed Image Text:### Chemical Reaction Problems #### Problem p. - **Reactant**: A linear alkyne compound - **Reagent**: \( \text{Cl}_2 \, (\text{excess}) \) - **Description**: The alkyne undergoes halogenation with excess chlorine. #### Problem q. - **Reactant**: A branched alkyne - **Reagent**: \( \text{Br}_2 \) - **Description**: The alkyne is treated with bromine for halogenation. #### Problem r. - **Reactant**: An internal alkyne - **Reagents**: 1. \( \text{NaNH}_2 \) 2. \( \text{CH}_3\text{Br} \) - **Description**: The alkyne undergoes deprotonation with sodium amide, followed by alkylation using methyl bromide. #### Problem s. - **Reactant**: A branched alkyne - **Reagent**: \( \text{Cl}_2 \, (\text{excess}) \) - **Description**: Halogenation of the alkyne using an excess of chlorine. #### Problem t. - **Reactant**: A linear alkyne - **Reagents**: 1. \( \text{NaNH}_2 \) 2. \( \text{BrCH}_2CH_3 \) - **Description**: The alkyne is first treated with sodium amide for deprotonation, followed by alkylation using bromoethane.
Expert Solution
Step 1: Reaction of alkyne

Alkyne is an electron riched system, hence addition reaction takes place. 

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