Ozone can oxidize HSO3^1-(aq) as represented below:   HSO3^-(aq)+03(aq)---> HSO4^-(aq) +02(g)   A solution is prepared in which the initial concentration of HSO3^1- (aq)(6.4x10^-4M) is much larger than that of O3(aq)(1.0x10^-5M). The concentration of O3(aq) is monitored as the reaction proceeds, and the data are plotted in the graph below: (see attached image)   iii)Considering the relative concentration of the reactants, briefly explain why the data in the graph are also consistent with the following rate law: Rate=k1[O3][HSO3^1-] iv)Briefly describe an experiment that could provide evidence to support the rate law given in part (diii)

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Chapter10: Energy
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Ozone can oxidize HSO3^1-(aq) as represented below:
 
HSO3^-(aq)+03(aq)---> HSO4^-(aq) +02(g)
 
A solution is prepared in which the initial concentration of HSO3^1-
(aq)(6.4x10^-4M) is much larger than that of O3(aq)(1.0x10^-5M). The concentration of O3(aq) is monitored as the reaction proceeds, and the data are plotted in the graph below: (see attached image)
 
iii)Considering the relative concentration of the reactants, briefly explain why the data in the graph are also consistent with the following rate law: Rate=k1[O3][HSO3^1-]
iv)Briefly describe an experiment that could provide evidence to support the rate law given in part (diii)
 
1.0 x 105.
8.0 x 10-6.
6.0 x 10-6.
4.0 x 10-5.
2.0 x 10 6.
0.
0 .0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10
Time (s)
['ol
Transcribed Image Text:1.0 x 105. 8.0 x 10-6. 6.0 x 10-6. 4.0 x 10-5. 2.0 x 10 6. 0. 0 .0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.10 Time (s) ['ol
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