Homework Help is Here – Start Your Trial Now!
Engineering
Chemical Engineering
Orthonitroanaline (an important intermediate in dyes-called fast orange) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia (see explosion in Figure E13-2.1 in Example 13-2). P4-6A NO, NO, NH, + NH,CI + 2NH, The liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m/kmol - min at 188°C with E = 11,273 cal/mol. The initial entering concentrations of ONCB and ammonia are 1.8 kmol/m' and 6.6 kmol/m', respectively (more on this reaction in Chapter 13). (a) Set up a stoichiometric table for this reaction for a flow system. (b) Write the rate law for the rate of disappearance of ONCB in terms of concentration. (c) Explain how parts (a) and (b) would be different for a batch system.

Orthonitroanaline (an important intermediate in dyes-called fast orange) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia (see explosion in Figure E13-2.1 in Example 13-2). P4-6A NO, NO, NH, + NH,CI + 2NH, The liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m/kmol - min at 188°C with E = 11,273 cal/mol. The initial entering concentrations of ONCB and ammonia are 1.8 kmol/m' and 6.6 kmol/m', respectively (more on this reaction in Chapter 13). (a) Set up a stoichiometric table for this reaction for a flow system. (b) Write the rate law for the rate of disappearance of ONCB in terms of concentration. (c) Explain how parts (a) and (b) would be different for a batch system.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
See similar textbooks
icon
Related questions
Question
P4-6A Orthonitroanaline (an important intermediate in dyes-called fast orange) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia (see explosion in Figure E13-2.1 in Example 13-2). NO2 NH, NO, + 2NH, + NH,CI The liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m/kmol - min at 188°C with E = 11,273 cal/mol. The initial entering concentrations of ONCB and ammonia are 1.8 kmol/m' and 6.6 kmol/m', respectively (more on this reaction in Chapter 13). (a) Set up a stoichiometric table for this reaction for a flow system. (b) Write the rate law for the rate of disappearance of ONCB in terms of concentration. (c) Explain how parts (a) and (b) would be different for a batch system. (d) Write-rA solely as a function of conversion. (e) What is the initial rate of reaction (X = 0) at 188°C? at 25°C? -TA = -YA = at 288°C? at 188°C? (f) What is the rate of reaction when X 0.90 -A = at 25°C? -YA = at 288°C? -A = 144 Stoichiometry Chapter 4 (g) What would be the corresponding CSTR reactor volume at 25°C to achieve 90% conversion and at 288°C for a feed rate of 2 dm/min V = V = at 25°C? at 288°C?
Transcribed Image Text:P4-6A Orthonitroanaline (an important intermediate in dyes-called fast orange) is formed from the reaction of orthonitrochlorobenzene (ONCB) and aqueous ammonia (see explosion in Figure E13-2.1 in Example 13-2). NO2 NH, NO, + 2NH, + NH,CI The liquid-phase reaction is first order in both ONCB and ammonia with k = 0.0017 m/kmol - min at 188°C with E = 11,273 cal/mol. The initial entering concentrations of ONCB and ammonia are 1.8 kmol/m' and 6.6 kmol/m', respectively (more on this reaction in Chapter 13). (a) Set up a stoichiometric table for this reaction for a flow system. (b) Write the rate law for the rate of disappearance of ONCB in terms of concentration. (c) Explain how parts (a) and (b) would be different for a batch system. (d) Write-rA solely as a function of conversion. (e) What is the initial rate of reaction (X = 0) at 188°C? at 25°C? -TA = -YA = at 288°C? at 188°C? (f) What is the rate of reaction when X 0.90 -A = at 25°C? -YA = at 288°C? -A = 144 Stoichiometry Chapter 4 (g) What would be the corresponding CSTR reactor volume at 25°C to achieve 90% conversion and at 288°C for a feed rate of 2 dm/min V = V = at 25°C? at 288°C?
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The
SEE MORE TEXTBOOKS