Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C₂(NO₂)6. decomposes according to the equation C₂(NO2)6-2NO2+ 4NO+2CO₂ The reaction in CCl4 solvent is first order with respect to C₂(NO₂). At 68.9 °C, k = 0.000333 s¹ and at 108.0 °C, k = 0.0176s¹. (a) What is the half-life of C₂(NO₂)6 at 68.9 °C? eTextbook and Media (b) What is the half-life of C₂(NO₂)6 at 108.0°C? seconds (c) If 0.100 mol of C₂(NO2)6 is dissolved in CCl4 at 68.9°C to give 1.00 L of solution, what will be the C₂(NO₂)6 concentration after 50.0 minutes? M (e) What is the rate constant at 153.1 °C? A seconds (d) What is the value of the activation energy of this reaction, expressed in kilojoules? $°2 kJ/mol
Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C₂(NO₂)6. decomposes according to the equation C₂(NO2)6-2NO2+ 4NO+2CO₂ The reaction in CCl4 solvent is first order with respect to C₂(NO₂). At 68.9 °C, k = 0.000333 s¹ and at 108.0 °C, k = 0.0176s¹. (a) What is the half-life of C₂(NO₂)6 at 68.9 °C? eTextbook and Media (b) What is the half-life of C₂(NO₂)6 at 108.0°C? seconds (c) If 0.100 mol of C₂(NO2)6 is dissolved in CCl4 at 68.9°C to give 1.00 L of solution, what will be the C₂(NO₂)6 concentration after 50.0 minutes? M (e) What is the rate constant at 153.1 °C? A seconds (d) What is the value of the activation energy of this reaction, expressed in kilojoules? $°2 kJ/mol
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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