|Below is a graph of the enthalpy change on mixing for the binary mixtur trichloromethane (x1) and ethanol (x2) at 30 °C. The values are in J/mol. At this mperature the pure molar enthalpies of each component are equal to zero. At a mixture of x1 = 0.1, determine whether or not the partial molar enthalpies c each component ( H, and H,) are greater, less than, or equal to zero.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter16: Thermodynamics: Directionality Of Chemical Reactions
Section: Chapter Questions
Problem 121QRT
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Below is a graph of the enthalpy change on mixing for the binary mixture
of trichloromethane (x1) and ethanol (x2) at 30 °C. The values are in J/mol. At this
temperature the pure molar enthalpies of each component are equal to zero.
a) At a mixture of x1 = 0.1, determine whether or not the partial molar enthalpies of
each component ( H, and H,) are greater, less than, or equal to zero.
b)
At a mixture of x1 = 0.5, determine whether or not the partial molar enthalpies of
each component ( H, and H,) are greater, less than, or equal to zero
600
400
200
-200
-400
-600,
0.2
0.4
0.6
0.8
1
X,
AmiH
Transcribed Image Text:Below is a graph of the enthalpy change on mixing for the binary mixture of trichloromethane (x1) and ethanol (x2) at 30 °C. The values are in J/mol. At this temperature the pure molar enthalpies of each component are equal to zero. a) At a mixture of x1 = 0.1, determine whether or not the partial molar enthalpies of each component ( H, and H,) are greater, less than, or equal to zero. b) At a mixture of x1 = 0.5, determine whether or not the partial molar enthalpies of each component ( H, and H,) are greater, less than, or equal to zero 600 400 200 -200 -400 -600, 0.2 0.4 0.6 0.8 1 X, AmiH
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