One mol of O2(g) undergoes a transformation from the initial state T 300 K and %D V1 20.0 L to the final state T2 400 K and V2 2.0 L. In this regime O2(g) is reasonably well described by the van der Waals equation of state, with constants 1.364 atm L? mol-2 and b = 3.19 × 10–2 L mol¬'. Also in this temperature range the molar heat capacity at constant volume of O2(g) has the approximately constant value 20.8 J K-l mol-1. Recalling that for a van der Waals gas n? a V? Ae T what is the internal energy change AU of the gas in the transformation (T1, V1) → (T2, V2)?

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One mol of O2(g) undergoes a transformation from the initial state T1
300 K and
V1
20.0L to the final state T2
400 K and V2
2.0 L. In this regime O2(g) is
reasonably well described by the van der Waals equation of state, with constants
1.364 atm L? mol-2 and b = 3.19 × 10-2 L mol-. Also in this temperature range
a =
the molar heat capacity at constant volume of O2(g) has the approximately constant
value 20.8 J K-l mol-1. Recalling that for a van der Waals gas
n? a
Əv
T
V2 '
what is the internal energy change AU of the gas in the transformation (T1, V1) –→
(Тэ, V2)?
Transcribed Image Text:One mol of O2(g) undergoes a transformation from the initial state T1 300 K and V1 20.0L to the final state T2 400 K and V2 2.0 L. In this regime O2(g) is reasonably well described by the van der Waals equation of state, with constants 1.364 atm L? mol-2 and b = 3.19 × 10-2 L mol-. Also in this temperature range a = the molar heat capacity at constant volume of O2(g) has the approximately constant value 20.8 J K-l mol-1. Recalling that for a van der Waals gas n? a Əv T V2 ' what is the internal energy change AU of the gas in the transformation (T1, V1) –→ (Тэ, V2)?
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