Use the van der Waals equation of state to calculate the pressure ? of 4.00 mol of CH4 at 469 K in a 4.20 L vessel

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Use the van der Waals equation of state to calculate the pressure ? of 4.00 mol of CH4 at 469 K in a 4.20 L vessel

a
а
Gas
b (L/mol)
(bar · L2 /mol 2) (atm · L2 /mol 2 )
2.273
CH4
CO2
Cl2
2.303
0.0431
3.658
3.610
0.0429
6.343
6.260
0.0542
NH3
4.225
4.170
0.0371
H20
Хе
CI4
02
N2
Kr
5.465
5.537
4.192
0.0305
0.0516
4.137
19.75
20.01
0.1281
1.382
1.363
0.0319
1.370
1.351
0.0387
Ar
CO
H2S
5.193
1.355
1.472
4.544
5.121
1.336
1.452
0.0106
0.0320
0.0395
0.0434
4.481
NO
N20
1.370
3.852
1.351
3.799
0.0387
0.0444
NO2
SO2
5.36
5.29
0.0443
6.770
9.431
3.648
4.437
6.221
0.0568
6.865
9.565
3.700
4.500
6.309
0.0739
HF
HCl
0.0406
0.0442
0.0530
HBr
HI
Transcribed Image Text:a а Gas b (L/mol) (bar · L2 /mol 2) (atm · L2 /mol 2 ) 2.273 CH4 CO2 Cl2 2.303 0.0431 3.658 3.610 0.0429 6.343 6.260 0.0542 NH3 4.225 4.170 0.0371 H20 Хе CI4 02 N2 Kr 5.465 5.537 4.192 0.0305 0.0516 4.137 19.75 20.01 0.1281 1.382 1.363 0.0319 1.370 1.351 0.0387 Ar CO H2S 5.193 1.355 1.472 4.544 5.121 1.336 1.452 0.0106 0.0320 0.0395 0.0434 4.481 NO N20 1.370 3.852 1.351 3.799 0.0387 0.0444 NO2 SO2 5.36 5.29 0.0443 6.770 9.431 3.648 4.437 6.221 0.0568 6.865 9.565 3.700 4.500 6.309 0.0739 HF HCl 0.0406 0.0442 0.0530 HBr HI
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