On the basis of solubility behavior, show how each of the following pairs of compounds may be distinguished from each other: a. CH3COOH and CH3(CH2)5COOH b. CH3CH2OCH2CH3 and CH3CH2OH c. Toluene and benzaldehyde d. Tert-butyl chloride and tert-butanol

On the basis of solubility behavior, show how each of the following pairs of compounds may be distinguished from each other: a. CH3COOH and CH3(CH2)5COOH b. CH3CH2OCH2CH3 and CH3CH2OH c. Toluene and benzaldehyde d. Tert-butyl chloride and tert-butanol

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter28: Nitration Of Methyl Benzoate

Section: Chapter Questions

Problem 1Q

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Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

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On the basis of solubility behavior, show how each of the following pairs of compounds may be distinguished from each other:

a. CH3COOH and CH3(CH2)5COOH
b. CH3CH2OCH2CH3 and CH3CH2OH
c. Toluene and benzaldehyde
d. Tert-butyl chloride and tert-butanol

Determine the best solvent to differentiate the following

1. Methylamine and Hexanamine

2. phenol and hexanoic acid

3. p-xylene and benzaldehyde

4. chloroform and tert-butanol

5. glucose and n-butanol

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