On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 28.0 °C using the following equation: AG-RT In Keq The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor
On a separate sheet of paper, draw the two alternative chair conformations for the product formed by the addition of bromine to 4-tert-butylcyclohexene. The Gibbs free-energy differences between equatorial and axial substituents on a cyclohexane ring are 21 kJ/mol for tert-butyl, and 2.3 kJ/mol for bromine. Calculate the ratio of the two observed products at 28.0 °C using the following equation: AG-RT In Keq The gas constant, R, is 8.314 J/K-mol. (Enter your answer to two significant figures.) Ratio: Major to 1 Minor
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.45P: Gibbs free energy differences between axial-substituted and equatorial-substituted chair...
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