O A way to measure the Ksp of an ionic compound is to redre the metal cation and measure the cell potential. The Solld compound AgSCN was reduced and the potential was measured under standard conditions to be the following E 0.09 V ABSCN (s) +e Ag (s) + SCN (aq) Using the reduction potential for Ag" (aq) in the appendix, find Ksp for AgsCN.

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* Away to measure the Ksp of an ionic compound is to reduce the metal cation and measure the cell potential. The
Solld compound AgSCN was reduced and the potenrial war m ured under standard conditions to be the following
ABSCN (s) +e Ag (s) + SCN (ag)
E= +0.09 V
Using the reduction potential for Ag (aq) in the appendix, find Ksp for AgSCN.
9. A voltaic cell is constructed using the following
Fe (s) + 2H" (aq) - H, (g) + Fe" (aq)
a. What is the potential under standard conditions?
b. What is the potential when [Fe"]= 1.25 M, P 1.15 atm, and the pH in both cells is 4,75 at 298 K?
c. What is the Gibb's Free Energy and the equilibrium constant, K under standard conditions? What are these
values with the conditions of part b? Did the reaction become more or less spontaneous? Explain.
Transcribed Image Text:* Away to measure the Ksp of an ionic compound is to reduce the metal cation and measure the cell potential. The Solld compound AgSCN was reduced and the potenrial war m ured under standard conditions to be the following ABSCN (s) +e Ag (s) + SCN (ag) E= +0.09 V Using the reduction potential for Ag (aq) in the appendix, find Ksp for AgSCN. 9. A voltaic cell is constructed using the following Fe (s) + 2H" (aq) - H, (g) + Fe" (aq) a. What is the potential under standard conditions? b. What is the potential when [Fe"]= 1.25 M, P 1.15 atm, and the pH in both cells is 4,75 at 298 K? c. What is the Gibb's Free Energy and the equilibrium constant, K under standard conditions? What are these values with the conditions of part b? Did the reaction become more or less spontaneous? Explain.
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