Note: Derive the expression relating the two kinetic constants first before plugging the values. mol Chemist 1 performed density - functional theory calculations for a certain reaction and found its activation energy is 29,695 Chemist 1 then claimed that the reaction obeys the collision theory. However, the Chemist 2 argued that the hypothesis of Chemist 1 is incorrect. According to the Chemist 2, the reaction follows the Arrhenius - type temperature dependency. Chemist 2 conducted an experiment in an ideal constant volume batch reactor to prove this. The results of the kinetic analysis revealed that k = 0.005s¹ at T = 298 K and k = 0.07 s-¹ at T =373 K. Using this data, what is the correct temperature dependency mechanism that the reaction obeys? Justify your answer using calculated values of activation energy using each theory
Note: Derive the expression relating the two kinetic constants first before plugging the values. mol Chemist 1 performed density - functional theory calculations for a certain reaction and found its activation energy is 29,695 Chemist 1 then claimed that the reaction obeys the collision theory. However, the Chemist 2 argued that the hypothesis of Chemist 1 is incorrect. According to the Chemist 2, the reaction follows the Arrhenius - type temperature dependency. Chemist 2 conducted an experiment in an ideal constant volume batch reactor to prove this. The results of the kinetic analysis revealed that k = 0.005s¹ at T = 298 K and k = 0.07 s-¹ at T =373 K. Using this data, what is the correct temperature dependency mechanism that the reaction obeys? Justify your answer using calculated values of activation energy using each theory
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.60P
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Note: Derive the expression relating the two kinetic constants first before plugging the values. please do not use excel. show all the necessary step/solutions. please answer all.
Transcribed Image Text:Note: Derive the expression relating the two kinetic constants first
before plugging the values.
mol
Chemist 1 performed density - functional theory calculations for a certain
reaction and found its activation energy is 29,695 Chemist 1 then
claimed that the reaction obeys the collision theory. However, the Chemist 2
argued that the hypothesis of Chemist 1 is incorrect. According to the
Chemist 2, the reaction follows the Arrhenius - type temperature
dependency. Chemist 2 conducted an experiment in an ideal constant
volume batch reactor to prove this. The results of the kinetic analysis
revealed that k = 0.005s¹ at T = 298 K and k = 0.07 s-¹ at T =373 K. Using
this data, what is the correct temperature dependency mechanism that the
reaction obeys? Justify your answer using calculated values of activation
energy using each theory.
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