NO + O3 --> NO2 + O2 (1) NO2 + hv --> NO + O3 (in the presence of O2) (2) With k1=2.2x10-12 exp(-1430/T) cm3 molecule-1s-1 and k2=1x10-2 s-1 (ie, at noon).  Calculate the steady-state concentration of NO and NO2 at noon based on the above reactions.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.11QAP
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NO + O3 --> NO2 + O2 (1)
NO2 + hv --> NO + O3 (in the presence of O2) (2)

With k1=2.2x10-12 exp(-1430/T) cm3 molecule-1s-1 and k2=1x10-2 s-1 (ie, at noon).

 Calculate the steady-state concentration of NO and NO2 at noon based on the above
reactions. 

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