Nitroalkanes are about as acidic as ketones and aldehydes. Nitroalkanes can also be utilized in reactions similar to the Aldol reaction (a reaction termed a Henry reaction). a) Rationalize why nitroalkanes are more acidic than alkanes. b) Provide a mechanism for both steps of the following Aldol-like (Henry) reaction.
Nitroalkanes are about as acidic as ketones and aldehydes. Nitroalkanes can also be utilized in reactions similar to the Aldol reaction (a reaction termed a Henry reaction). a) Rationalize why nitroalkanes are more acidic than alkanes. b) Provide a mechanism for both steps of the following Aldol-like (Henry) reaction.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Nitroalkanes are about as acidic as ketones and aldehydes. Nitroalkanes can also be utilized
in reactions similar to the Aldol reaction (a reaction termed a Henry reaction). a) Rationalize
why nitroalkanes are more acidic than alkanes. b) Provide a mechanism for both steps of the
following Aldol-like (Henry) reaction.
base
conjugate base
base
less stable conjugate base
NO2
(b)
NO2
но
NO2
- H20
H.
H.
кон
O=Z
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