Nitrite (NO2) can be determined by oxidation with excess Ce4*, followed by back titration of the unreacted Ce4*. A 4.030-g sample of solid conto only NANO2 (FM 68.995) and NaNO3 was dissolved in 500.0 mL. A 25.00-mL sample of this solution was treated with 50.00 mL of 0.118 6 M Ce4*in: acid for 5 min, and the excess Ce4* was back-titrated with 31.13 mL of 0.04289 M ferrous ammonium sulfate. Calculate the weight percent of Na he solid. 2Ce** + NO, + H2O → 2Ce³*+ + NO, + 2H* E3+

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Nitrite (NO2) can be determined by oxidation with excess Ce4*, followed by back titration of the unreacted Ce4*. A 4.030-g sample of solid containing
only NANO2 (FM 68.995) and NANO3 was dissolved in 500.0 mL. A 25.00-mL sample of this solution was treated with 50.00 ml of 0.118 6 M Ce4*in strong
acid for 5 min, and the excess Ce4* was back-titrated with 31.13 ml of 0.04289 M ferrous ammonium sulfate. Calculate the weight percent of NANO2 in
the solid.
2Ce** + NO, + H2O → 2Ce³* + NO, + 2H*
Ce*+ + Fe2+ → Ce³+ + Fe3+
Show your solutions by sending your answers.
Transcribed Image Text:Nitrite (NO2) can be determined by oxidation with excess Ce4*, followed by back titration of the unreacted Ce4*. A 4.030-g sample of solid containing only NANO2 (FM 68.995) and NANO3 was dissolved in 500.0 mL. A 25.00-mL sample of this solution was treated with 50.00 ml of 0.118 6 M Ce4*in strong acid for 5 min, and the excess Ce4* was back-titrated with 31.13 ml of 0.04289 M ferrous ammonium sulfate. Calculate the weight percent of NANO2 in the solid. 2Ce** + NO, + H2O → 2Ce³* + NO, + 2H* Ce*+ + Fe2+ → Ce³+ + Fe3+ Show your solutions by sending your answers.
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