Natural gas and petroleum deposits make up the world’s largest source of alkanes. Refinement of petroleum followed by distillation produces fuels for vehicles where the fuels undergo combustion. However, not all fuels are judged as  “good fuel”, some are “poor  fuel”. Hence, the “octane number” was developed to determine the type of fuel. Why is the straight-chain alkane octane considered as poor fuel with an octane number = 0 and a branched-chain alkane 2,2,4-Trimethylpentane with an octane number = 100?

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Chapter22: Organic And Biological Molecules
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  1. Natural gas and petroleum deposits make up the world’s largest source of alkanes. Refinement of petroleum followed by distillation produces fuels for vehicles where the fuels undergo combustion. However, not all fuels are judged as  “good fuel”, some are “poor  fuel”. Hence, the “octane number” was developed to determine the type of fuel. Why is the straight-chain alkane octane considered as poor fuel with an octane number = 0 and a branched-chain alkane 2,2,4-Trimethylpentane with an octane number = 100?
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