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H₂O OH ď OH 2. Neutralizing work-up H₂O* TSOH, H₂O [a] A mCPBA H₂O* 1. BH-THF 2.H₂O₂, NaOH Bra H₂O 1. OsO. (catalytic) 2. NMO

H₂O OH ď OH 2. Neutralizing work-up H₂O* TSOH, H₂O [a] A mCPBA H₂O* 1. BH-THF 2.H₂O₂, NaOH Bra H₂O 1. OsO. (catalytic) 2. NMO

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Select the missing reagents in the following multistep synthesis. Ignore any inorganic byproducts formed. 'H Š H O H₂O OH @ 1. NaOH, heat 2. Neutralizing work-up 1 H3O+ O TSOH, H₂O O H a A B C D E HOCH2CH2CH₂OH NaOH HOCH2CH2CH₂OH TSOH HOCH2CH2CH₂OH H₂O TSOH, H₂O CH₂OH(2 eq) TSOH
Transcribed Image Text:Select the missing reagents in the following multistep synthesis. Ignore any inorganic byproducts formed. 'H Š H O H₂O OH @ 1. NaOH, heat 2. Neutralizing work-up 1 H3O+ O TSOH, H₂O O H a A B C D E HOCH2CH2CH₂OH NaOH HOCH2CH2CH₂OH TSOH HOCH2CH2CH₂OH H₂O TSOH, H₂O CH₂OH(2 eq) TSOH
O H₂O OH O OH | a Q 2. Neutralizing work-up H3O+ TSOH, H₂O O A B C D E mCPBA H3O+ 1. BH3-THF 2.H₂O2, NaOH Br₂ H₂O 1. OsO4 (catalytic) 2. NMO
Transcribed Image Text:O H₂O OH O OH | a Q 2. Neutralizing work-up H3O+ TSOH, H₂O O A B C D E mCPBA H3O+ 1. BH3-THF 2.H₂O2, NaOH Br₂ H₂O 1. OsO4 (catalytic) 2. NMO
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The last reaction is either C, D, or E. 

NaOH OH OH Q < 1. BH3-THF 2.H₂O2, NaOH HOCH2CH2CH2 OH TSOH A B C D E NaOH H₂O HOCH₂CH2CH2OH TSOH, H₂O TSOH, H₂O HgCl2, H2SO4
Transcribed Image Text:NaOH OH OH Q < 1. BH3-THF 2.H₂O2, NaOH HOCH2CH2CH2 OH TSOH A B C D E NaOH H₂O HOCH₂CH2CH2OH TSOH, H₂O TSOH, H₂O HgCl2, H2SO4
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