Formal Charges
Formal charges have an important role in organic chemistry since this concept helps us to know whether an atom in a molecule is neutral/bears a positive or negative charge. Even if some molecules are neutral, the atoms within that molecule need not be neutral atoms.
Polarity Of Water
In simple chemical terms, polarity refers to the separation of charges in a chemical species leading into formation of two polar ends which are positively charged end and negatively charged end. Polarity in any molecule occurs due to the differences in the electronegativities of the bonded atoms. Water, as we all know has two hydrogen atoms bonded to an oxygen atom. As oxygen is more electronegative than hydrogen thus, there exists polarity in the bonds which is why water is known as a polar solvent.
Valence Bond Theory Vbt
Valence bond theory (VBT) in simple terms explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. It gives a quantum mechanical approach to the formation of covalent bonds with the help of wavefunctions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
- Name the electron pair geometry and the molecular structure (shape) for each of the following molecules.
PCl3
SF4
IBr5
CO32-
NO2+
![**Educational Content for Chemistry: Understanding Molecular Structures and Bond Angles**
1. **Molecular Formulae:**
- PCl₃
- SF₄
- IBr₅
- CO₃²⁻
- NO₂⁺
2. **Bond Angles and Hybridization:**
For the following molecules, determine the bond angles indicated by arrows and describe the hybridization of the central atom.
![Molecule Structures](image)
- **Image 1:** The first structure shows a carbon-carbon double bond (C=C) in a hydrocarbon chain. The bond angle is highlighted around the central atoms involved in a double bond.
- **Image 2:** The second structure includes a triple bond between carbon and nitrogen (C≡N) with a focus on the bond angle at the carbon atom.
- **Image 3:** The third structure illustrates the bond angle around the nitrogen atom in a simple molecule containing hydrogen and oxygen.
3. **Butanone Analysis:**
Butanone is an organic compound with the general formula of CH₃CH₂COCH₃.
A) **Draw the Lewis Structure of Butanone:** Note that it contains a double bond.
B) **Describe Hybridization:** Describe the hybridization for each of the carbon atoms.
C) **Predict Bond Angles:** Indicate the bond angles around each of the carbon atoms.
D) **Determine Total Bonds:** Find the total number of σ bonds and π bonds in the molecule.
E) **Polarity of the Molecule:** Determine if the molecule is polar or non-polar and show dipole arrows if applicable.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F8bd6fd63-4954-40d4-8cee-f58b6e224360%2F1cff1b68-b6f4-4c90-9c2e-b8c2f1c92586%2F5n7oi4q_processed.png&w=3840&q=75)
![Module III - Homework 3
1. Name the electron pair geometry and the molecular structure (shape) for each of the following molecules.
- PCl₃
- SF₄
- IBr₅
- CO₃²⁻
- NO₂⁺
2. Give the values for the bond angles indicated by arrows and describe the hybridization of the central atom in each of the following molecules.
- Diagram 1: CH₃CHO (Acetaldehyde)
- Shows carbon bonded to hydrogen and a double-bonded oxygen with an arrow indicating the bond angle.
- Diagram 2: HCN (Hydrogen Cyanide)
- Shows hydrogen bonded to carbon, which is triple-bonded to nitrogen. Arrows indicate bond angles.
- Diagram 3: NH₃ (Ammonia)
- Shows nitrogen bonded to hydrogen atoms, with an arrow indicating the bond angle.
3. Butanone is an organic compound with the general formula of CH₃CH₂COCH₃.
- A) Draw the Lewis structure of Butanone. Note: there is a double bond.
- B) Describe the hybridization for each of the carbon atoms.
- C) Predict the bond angle around each of the carbon atoms.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F8bd6fd63-4954-40d4-8cee-f58b6e224360%2F1cff1b68-b6f4-4c90-9c2e-b8c2f1c92586%2Fvoz9dyu9_processed.png&w=3840&q=75)
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