NaHCO3 is an intermediate form of the diprotic acid carbonic acid H2CO3.What is the pH of 0.100 M NaHCO3 ?Carbonic acida) pH = 6.44b) pH = 7.25c) pH = 7.88d) pH = 8.34KA1 = 4.46 x 10-7PKA1 = 6.35KA2 4.69 x 10-11PKA2-10.33

The problem involves determining the pH of a 0.100 M solution of sodium bicarbonate (NaHCO₃). Sodium…

Answered: NaHCO3 is an intermediate form of the…

General, Organic, and Biological Chemistry

7th Edition

ISBN:9781285853918

Author:H. Stephen Stoker

Publisher:H. Stephen Stoker

Chapter10: Acids, Bases, And Salts

Section: Chapter Questions

Problem 10.19EP: Classify each of the following acids as monoprotic, diprotic, or triprotic. a. HClO3 (chloric acid)...

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For each of the following pairs of solutions, indicate whether the first listed solution has a higher or lower pH than the second listed solution. a. 1.0 M NaOH and 1.0 M HCl b. 1.0 M HNO3 and 0.10 M HNO3 c. 0.10 M HClO4 and 0.10 M HCN d. [H3O+] = 3.3 103 and [H3O+] = 9.3 103
What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?
Classify each of the following acids as monoprotic, diprotic, or triprotic. a. HClO3 (chloric acid) b. HC3H5O4 (glyceric acid) c. H3C6H5O7 (citric acid) d. H3PO4 (phosphoric acid)
Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?
Calculate the pH of each of the following solutions. (a) 10.0 mL of 0.300 M hydrofluoric acid plus 30.0 mL of 0.100 M sodium hydroxide (b) 100.0 mL of 0.250 M ammonia plus 50.0 mL of 0.100 M hydrochloric acid (c) 25.0 mL of 0.200 M sulfuric acid plus 50.0 mL of 0.400 M sodium hydroxide
(a) What is the pH of a 0.105 M HCl solution? (b) What is the hydronium ion concentration in a solution with a pH of 2.56? Is the solution acidic or basic? (c) A solution has a pH of 9.67. What is the hydronium ion concentration in the solution? Is the solution acidic or basic? (d) A 10.0-mL sample of 2.56 M HCl is diluted with water to 250. mL What is the pH of the dilute solution?
Methylammonium chloride is a salt of methylamine, CH3NH2. A 0.10 M solution of this salt has a pH of 5.82. a Calculate the value for the equilibrium constant for the reaction CH3NH3++H2OCH3NH2+H3O+ b What is the Kb value for methylamine? c What is the pH of a solution in which 0.450 mol of solid methylammonium chloride is added to 1.00 L of a 0.250 M solution of methylamine? Assume no volume change.
An aqueous solution contains formic acid and formate ion. Determine the direction in which the pH will change if each of the following chemicals is added to the solution. (a) HCl (b) NaHSO4 (c) CH3COONa (d) KBr (e) H2O
3. A solution has a pH of 10.54. What is the hydronium ion concentration? 2.9 × 10−11 M 2.7 × 10−5 M 10.54 M 3.5 × 1010 M
A buffer solution has a pH value of 9.8. Which value in the set of pH values 8.79.79.89.910.9 is the most likely value for the buffer solution pH after a. a small amount of strong acid has been added? b. a small amount of strong base has been added?
Calculate the pH and the pOH of each of the following solutions at 25 C for which the substances ionize completely: (a) 0.000259 M HClO4. (b) 0.21 M NaOH. (c) 0.000071 M Ba(OH)2. (d) 2.5 M KOH
What are the pH and ion concentrations in a solution of 0.10 M sodium formate, NaCHO2? Kb for the formate ion, HCO2 is 5.6 1011. pH [Na+] [CHO2] [OH] (a) 5.63 0.10 0.10 2.4 10-6 (b) 837 0.10 0.10 2.4 10 6 (c) 822 0.050 0.050 17 10- (d) 5.63 0.10 0.10 42 10

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NaHCO3 is an intermediate form of the diprotic acid carbonic acid H2CO3. What is the pH of 0.100 M NaHCO3 ? Carbonic acid a) pH = 6.44 b) pH = 7.25 c) pH = 7.88 d) pH = 8.34 KA1 = 4.46 x 10-7 PKA1 = 6.35 KA2 4.69 x 10-11 PKA2-10.33