N₂ has molecular orbitals rather similar to those of CO, as shown in Figure 13.12. Would you expect N₂ to be a stronger or weaker 7 acceptor than CO?

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EXERCISE 13.4
N₂ has molecular orbitals rather similar to those of CO, as shown in Figure 13.12.
Would you expect N₂ to be a stronger or weaker 7 acceptor than CO?
Transcribed Image Text:EXERCISE 13.4 N₂ has molecular orbitals rather similar to those of CO, as shown in Figure 13.12. Would you expect N₂ to be a stronger or weaker 7 acceptor than CO?
Bonding
The molecular orbital picture of CO is similar to that of N₂. Sketches of the molecular orbitals derived
primarily from the 2p AOs of these molecules are shown in Figure 13.12.
15
0.0
0-00-0
LUMO
0.0.0
HOMO
b
(:)
N₂
0.00.0
80
LUMO
O.(
0.0.0
HOMO
0:00
ос
CO
O
FIGURE 13.12 Selected
Molecular Orbitals of N₂ and CO.
Transcribed Image Text:Bonding The molecular orbital picture of CO is similar to that of N₂. Sketches of the molecular orbitals derived primarily from the 2p AOs of these molecules are shown in Figure 13.12. 15 0.0 0-00-0 LUMO 0.0.0 HOMO b (:) N₂ 0.00.0 80 LUMO O.( 0.0.0 HOMO 0:00 ос CO O FIGURE 13.12 Selected Molecular Orbitals of N₂ and CO.
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