Molecular orbitals in metals... A. Overlap significantly to allow free electron movement through the system. B. Have a large gap between bonding and valence bands so that electrons cannot easily be promoted to higher energy levels. C. Are so numerous because each atom contributes its atomic orbitals to a large network D. All of the above. E. Both A and C. O A OB OC OE OD

Chemistry for Engineering Students
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Chapter7: Chemical Bonding And Molecular Structure
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Problem 7.72PAE: 7.72 How does an MSN differ from amorphous silica so that is has improved biocompatibility?
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### Molecular Orbitals in Metals

When discussing molecular orbitals in metals, consider the following characteristics:

- **A. Overlap Significantly to Allow Free Electron Movement**: In metals, the overlap of molecular orbitals is significant, which facilitates the free movement of electrons throughout the system.
  
- **B. Have a Large Gap Between Bonding and Valence Bands**: This means that electrons cannot easily be promoted to higher energy levels because of the substantial energy gap.

- **C. Are Numerous**: Since each atom in a metal contributes its atomic orbitals to a collective network, the number of molecular orbitals is quite large.

- **D. All of the Above**: This implies that points A, B, and C collectively describe the properties of molecular orbitals in metals.

- **E. Both A and C**: This states that points A and C together describe significant aspects of molecular orbitals in metals.

#### Multiple Choice Options:
- **A**
- **B**
- **C**
- **E**
- **D** 

For educators, it is important to highlight that the correct answer is **D. All of the above**. This will help students understand that molecular orbitals in metals exhibit significant overlap, a large energy gap between bonding and valence bands, and are numerous due to the contribution of atomic orbitals from each atom.
Transcribed Image Text:### Molecular Orbitals in Metals When discussing molecular orbitals in metals, consider the following characteristics: - **A. Overlap Significantly to Allow Free Electron Movement**: In metals, the overlap of molecular orbitals is significant, which facilitates the free movement of electrons throughout the system. - **B. Have a Large Gap Between Bonding and Valence Bands**: This means that electrons cannot easily be promoted to higher energy levels because of the substantial energy gap. - **C. Are Numerous**: Since each atom in a metal contributes its atomic orbitals to a collective network, the number of molecular orbitals is quite large. - **D. All of the Above**: This implies that points A, B, and C collectively describe the properties of molecular orbitals in metals. - **E. Both A and C**: This states that points A and C together describe significant aspects of molecular orbitals in metals. #### Multiple Choice Options: - **A** - **B** - **C** - **E** - **D** For educators, it is important to highlight that the correct answer is **D. All of the above**. This will help students understand that molecular orbitals in metals exhibit significant overlap, a large energy gap between bonding and valence bands, and are numerous due to the contribution of atomic orbitals from each atom.
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