Molecular Orbitals 2. The carbon-oxygen single bond of carbonyls can be constructed using a mix of both hybridization and MO theory. Construct a MO diagram of the o bond of a carbonyl by mixing an oxygen sp² orbital and a carbon sp² orbital. Make sure your diagram is complete with all necessary orbitals (drawings of them), orbital notations, the proper number of electrons, and an appropriate energy ranking. Ọ

Molecular Orbitals 2. The carbon-oxygen single bond of carbonyls can be constructed using a mix of both hybridization and MO theory. Construct a MO diagram of the o bond of a carbonyl by mixing an oxygen sp² orbital and a carbon sp² orbital. Make sure your diagram is complete with all necessary orbitals (drawings of them), orbital notations, the proper number of electrons, and an appropriate energy ranking. Ọ

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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5. Among the most common over-the-counter drugs you might find in a medicine cabinet are mild pain relievers such ibuprofen (Advil, Motrin), naproxen (Aleve), and. acetaminophen (Tylenol). HO HO. HO. CH3 Ibuprofen Naproxen Acetaminophen a. How many sp3 hybridized carbons does each molecule have? b. How many sp2hybridized carbons does eacch molecule have? C. Can you spot any similarities in their structures?
Draw the molecular orbital (MO) electron diagram for the O2 molecular ion. Be sure your diagram contains all of the electrons in the ion, including any core electrons. Energy 1 L
Draw the molecular orbital diagram for HCI. Clearly label the axes, MO's, atomic orbitals. Show the distibution of the electrons in the MO's. Roughly sketch the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). Answer the next two questions based on your HCI MO diagram. Based on your MO diagram, what would be the bond order of HCI+2 jon? In the molecular orbital diagram of HCI, there are two non-bonding molecular orbitals with a total of 4 electrons occupying them. O True O False
24. Provide the hybridization and molecular geometry for the indicated atoms in the following molecules.
a. What is hybridization of carbon atom labeled "hybridization 3" b. Sigma (σ) bond between two carbon atoms (which DON'T have additional pi bond between them) is a combination of which two atomic orbitals according to the hybridization concept? c. Pi (π) bond between two carbon atoms is a combination of which two atomic orbitals according to the hybridization concept? d. Sigma (σ) bond between two carbon atoms (which are connected with pi bond as well) is a combination of which two atomic orbitals according to the hybridization concept? e. What is hybridization of oxygen atom labeled "hybridization 1" f. What is hybridization of carbon atom labeled "hybridization 2"
2) a) Consider the following molecule . Given what you have learned about hybridization theory, draw an image or images explaining the bonding situation in this molecule. I want you to draw out all of the orbitals, hybrid orbitals and how they overlap to form the bonds in the molecule. Indicate the % s or p character in the given atomic and hybrid orbitals. Which C-C bond or bonds are the longest? In a paragraph or so explain the image or images you just drew. b) Lastly, consider the molecule below. Indicate the Molecular formula, the molar mass, label the hybridization of each atom except for hydrogen, indicate any chiral centers with a *, which bond or bonds are the shortest, identify by name of each functional group with an arrow pointing to the group.
What is the total number of carbon atoms in this molecule? What is the total number of Hydrogen atoms in this molecule? i. How many sp3, sp2,and sp hybridized carbon atoms are in this compound?