Methyl isomerizes to acetonitrile, CH3NC(g) → CH3CN(g) at 215°C.  The following data were collected during the process: Time (sec) [CH3NC] (mol/L) 2000 0.0110 5000 0.0059 8000 0.0031 12000 0.0014 15000 0.0007 Use the following grids to plot three separate graphs of [CH3NC], ln [CH3NC], and 1/[CH3NC] against time to determine the reaction order. (a)Write the rate law expression in its general form. (b)Determine the rate constant. (c)Determine the half-life. (d)Assuming the process continues, what concentration of methyl isonitrile would we expect after 5.00 h?

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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  1. Methyl isomerizes to acetonitrile, CH3NC(g) → CH3CN(g) at 215°C.  The following data were collected during the process:

Time (sec)

[CH3NC] (mol/L)

2000

0.0110

5000

0.0059

8000

0.0031

12000

0.0014

15000

0.0007

Use the following grids to plot three separate graphs of [CH3NC], ln [CH3NC], and 1/[CH3NC] against time to determine the reaction order.

  1. (a)Write the rate law expression in its general form.
  2. (b)Determine the rate constant.
  3. (c)Determine the half-life.
  4. (d)Assuming the process continues, what concentration of methyl isonitrile would we expect after 5.00 h?
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