Match the compound to spectrum by drawing the structure next to correct spectrum. Then explain by describing the total number of signals each structure should have and which carbon would be farthest downfield.
Match the compound to spectrum by drawing the structure next to correct spectrum. Then explain by describing the total number of signals each structure should have and which carbon would be farthest downfield.
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter20: Molecular Mass Spectrometry
Section: Chapter Questions
Problem 20.11QAP
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Question
Match the compound to spectrum by drawing the structure next to correct spectrum. Then explain by describing the total number of signals each structure should have and which carbon would be farthest downfield.
![CH3
(a) (CH3)2CHCH,OH
(b)
`CH3
(c)
(d)
(e)
CH
CH3
Spectrum A
Spectrum B
TMS
TMS
CDC,
220 200 180 160 140 120 100 80
60
08
220 200 180 160 140 120 100
80
60
40
20
Chemical shift (ppm)
Chemical shift (ppm)
Spectrum C
Spectruin D
TMS
TMS
CDCI,
mimmm pmm m
220 200
20 200 180 160 140 120 100
80
60
10 20
180 160 140 120 100
60
90
40
20
08
Chemical shift (ppm)
Chemical shift (ppm)
in](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F577fda95-c267-4247-ba7e-28903bcfeb9a%2F7eb849d7-8ac5-444d-a883-88e91b9a845f%2Ffz2l91r_processed.png&w=3840&q=75)
Transcribed Image Text:CH3
(a) (CH3)2CHCH,OH
(b)
`CH3
(c)
(d)
(e)
CH
CH3
Spectrum A
Spectrum B
TMS
TMS
CDC,
220 200 180 160 140 120 100 80
60
08
220 200 180 160 140 120 100
80
60
40
20
Chemical shift (ppm)
Chemical shift (ppm)
Spectrum C
Spectruin D
TMS
TMS
CDCI,
mimmm pmm m
220 200
20 200 180 160 140 120 100
80
60
10 20
180 160 140 120 100
60
90
40
20
08
Chemical shift (ppm)
Chemical shift (ppm)
in
![Spectruim E
TMS
CDCI,.
220 200 180 160 140 120 100 80
60
40 20
08
Chemical shift (ppm)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F577fda95-c267-4247-ba7e-28903bcfeb9a%2F7eb849d7-8ac5-444d-a883-88e91b9a845f%2Fiz9sm7g_processed.png&w=3840&q=75)
Transcribed Image Text:Spectruim E
TMS
CDCI,.
220 200 180 160 140 120 100 80
60
40 20
08
Chemical shift (ppm)
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