MATCH a structure or term from the following list with each description below. Place the letter of thestructure or term in the blank to the left of the description.The reactive electrophile inFriedel-Crafts acylation reactions.[Choose ]R3C+The electrophile in aromatic+NO2nitration.electron-withdrawing+NOGroups which activate aromaticrings towards electrophilic substitution.Groups which activate aromaticrings towards nucleophilic substitution.electron-donatingbenzyneMeisenheimer complex[Choose ]Intermediate in the elimination-addition mechanism of nucleophilicaromatic substitution.[Choose ]

1. The reactive electrophile in Friedel-Crafts acylation reactions (R3C⁺): In Friedel-Crafts…

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Biochemistry

9th Edition

ISBN:9781319114671

Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.

Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.

Chapter1: Biochemistry: An Evolving Science

Section: Chapter Questions

Problem 1P

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For the following monosaccharide, draw the products formed when treated with each reagent. H H -OH HO H HO H H― -OH CH₂OH Part 1 of 2 H2 in the presence of a Pd catalyst. Modify the Fischer projection of the monosaccharide to represent the product. H H -ОН HO H HO H H -OH CH₂OH Part 2 of 2 Benedict's reagent. Modify the Fischer projection of the monosaccharide to represent the product. H H -OH HO -Н HO H H -OH CH₂OH ☐ : G ☐ E ☐: ☑ P G
Please see attached.
Curved arrows are used to illustrate the flow of electrons. Using the provided starting structure, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Then draw any missing organic intermediates or products for this epoxidation reaction. Include all lone pairs in the structures. Ignore inorganic byproducts, counterions, and solvents. 0. ~ H :OH: H Q H --0 Q mCPBA dilute HCI Select to Draw Intermediate 0:0 NaOH :OH: H Select to Add Arrows H I I I I I I I I I I
2. a. Label the following structures as ATP, ADP, AMP, P₁, PPi, or Adenosine. Place your answers in the boxes provided. HO H OH H OH OH O N. H H OH + ATP NH₂ . + ADP 01210 ++++++ O-AMP O O Adenosine *+-+ O 0=210 HO b. Put an "X" in the box for the reaction that is thermodynamically most favorable. OH OPP OPP Adenine + AMP + Adenosine
Modify the structure to show the MAJOR product that would be formed in the following reaction. HNO3, H2SO4
None
label all 5 identified regions in the active site, (labels like basic catalytic residue, acidic catalytic residue, catalytic nucleophile, etc.)
Give the IUPAC name for each aldehyde. Part 2 of 2 Part 1 of 2 CH. རས་པས་ CHỊCH,CH, CCH,CH,CHCH,CHO ། CH, 3-ethyl-6,6-dimethylnonanal CH,CH, ྾ ྾ 6
Which of the compounds shown below exhibit a high negative free energy of hydrolysis equal to or larger than the free energy of hydrolysis for the phosphoanhydride of ATP? (Choose all that apply) В Α HPΗ Ho HO HO H2N-CH-C CH2 H2N-CH-C CH2 CH2 H2N-CH-Ö CH2 C CH2 D E O A O B O E O=p-00 O=p-00 O=-00 O=0-00 O=L-00
What kind of catalysis is cysteine driving in this picture? S Los i fy R……—NHR N-H---S O. N-H H-N H-N. O Metal catalysis Covalent catalysis Base catalysis O Acid catalysis NHR²
Consider the structure shown below. он 3 5 CH; O CH, O H CH; O 1 H-N-CH,-C-N-CH;-C-N-CH-C-N-CH-C-N-CH-C-ơ 2 H. H H Fill in the blank with an integer (1, 2, 3, 4, 5..) as shown in the diagram or to represent a specified number. A hydrophilic side chain is indicated by the number
Draw the major organic product of the following reaction sequence. .COzH CH3COCI, pyridine

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