Many cyclic organic compounds that contain two carbon-carbon double bonds undergo a dimerization reaction to give complex structures. One example is as follows: Me Ph Ph Ph Me Me Me Me Ph Me Me Me Ph Ph Ph Ph 2 monomers (red) dimer (colorless) The following data as obtained experimentally, where the monomer concentration was monitored at various times during the experiment, as depicted below. Time/min Monomer[M] 0.0054 10 0.0044 26 0.0034 44 0.0027 70 0.0020 120 0.0014 a. Using a graph method of the Integrated Rate Law to determine if the reaction obeys first order or second order reaction kinetics. 90 b. From your graph determine the rate constant, k, for the reaction.

Fundamentals Of Analytical Chemistry
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Chapter30: Kinetic Methods Of Analysis
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Problem 30.13QAP
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QUESTION SIX
Many cyclic organic compounds that contain two carbon-carbon double bonds undergo a dimerization
reaction to give complex structures. One example is as follows:
I| Me
Ph Ph
Ph.
Me.
Me
Me.
Me
Ph
Me
Me
Ph
Ph
Ph
Ph
Me
2 monomers
dimer
(red)
(colorless)
The following data as obtained experimentally, where the monomer concentration was monitored at
various times during the experiment, as depicted below.
Time/min Monomer[M]
0.0054
10
0.0044
26
0.0034
44
0.0027
70
0.0020
120
0.0014
a. Using a graph method of the Integrated Rate Law to determine if the reaction obeys first order or
second order reaction kinetics.
90
b. From your graph determine the rate constant, k, for the reaction.
Transcribed Image Text:QUESTION SIX Many cyclic organic compounds that contain two carbon-carbon double bonds undergo a dimerization reaction to give complex structures. One example is as follows: I| Me Ph Ph Ph. Me. Me Me. Me Ph Me Me Ph Ph Ph Ph Me 2 monomers dimer (red) (colorless) The following data as obtained experimentally, where the monomer concentration was monitored at various times during the experiment, as depicted below. Time/min Monomer[M] 0.0054 10 0.0044 26 0.0034 44 0.0027 70 0.0020 120 0.0014 a. Using a graph method of the Integrated Rate Law to determine if the reaction obeys first order or second order reaction kinetics. 90 b. From your graph determine the rate constant, k, for the reaction.
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