M+1 and M+2 relative eak). Use the isotope d. C10H19CI e. CioH19Br

Macroscale and Microscale Organic Experiments
7th Edition
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Kenneth L. Williamson, Katherine M. Masters
Chapter13: Mass Spectrometry
Section: Chapter Questions
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Do NOT answer A-D only E
7. Calculate the expected M+1 and M+2 relative intensities assuming M+ has a relative
intensity of 100% (base peak). Use the isotope masses contained in the table below.
a. CioH20
d. C10H19CI
b. C8H12O2
e. CioH19Br
c. C3H16N2
Transcribed Image Text:7. Calculate the expected M+1 and M+2 relative intensities assuming M+ has a relative intensity of 100% (base peak). Use the isotope masses contained in the table below. a. CioH20 d. C10H19CI b. C8H12O2 e. CioH19Br c. C3H16N2
Element
Natural abundance
Carbon
12C
13C
98.89%
1.11%
Hydrogen
2H
99.99%
0.01%
Nitrogen
14N
15N
99.64%
0.36%
Oxygen
160
170
99.76%
0.04%
0.20%
32s
33S
34S
36S
Sulfur
0.76%
4.22%
0.02%
95.0%
Fluorine
19F
100%
35CI
37CI
Chlorine
24.23%
75.77%
8IBr
Bromine
50.69%
49.31%
Transcribed Image Text:Element Natural abundance Carbon 12C 13C 98.89% 1.11% Hydrogen 2H 99.99% 0.01% Nitrogen 14N 15N 99.64% 0.36% Oxygen 160 170 99.76% 0.04% 0.20% 32s 33S 34S 36S Sulfur 0.76% 4.22% 0.02% 95.0% Fluorine 19F 100% 35CI 37CI Chlorine 24.23% 75.77% 8IBr Bromine 50.69% 49.31%
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