Looking at a d6 Tanabe-Sugano diagram needed to assign the electronic transistion that corresponds to (lambda)max off 550 nm. Give that the Racah parameter for the iron complex in this complex is 848 cm^-1, determine the lighand field parameter in cm^-1 for the complex in the spin-state associated with lambda max. complex: [Fe(NH2trz)3]Cl2·2H2O

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Looking at a d6 Tanabe-Sugano diagram needed to assign the electronic transistion that corresponds to (lambda)max off 550 nm. Give that the Racah parameter for the iron complex in this complex is 848 cm^-1, determine the lighand field parameter in cm^-1 for the complex in the spin-state associated with lambda max.

complex: [Fe(NH2trz)3]Cl2·2H2O

 

do Tanabe-Sugano Diagram
3
3
2g
1g
2g
3T
2g
3 Ars
5T 29
1T 2g
70
60
3P
1T1g
3T.
50
1F
2g
3T.
1g
40
'G, 'I
30
3F, ³G
3H
20
10
5T
1g
5D
2g
40
50
10
20
A/B
30
80
E/B
Transcribed Image Text:do Tanabe-Sugano Diagram 3 3 2g 1g 2g 3T 2g 3 Ars 5T 29 1T 2g 70 60 3P 1T1g 3T. 50 1F 2g 3T. 1g 40 'G, 'I 30 3F, ³G 3H 20 10 5T 1g 5D 2g 40 50 10 20 A/B 30 80 E/B
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