LOD 透过率/% D 12.2 Which compound is consistent with the spectrum shown below? 薄膜法 wp 1500 /cm-¹ 4000 (a) 3000 (b) .OH 2000 HOT (c) OH (d) 1000 NH₂ (e) 500
LOD 透过率/% D 12.2 Which compound is consistent with the spectrum shown below? 薄膜法 wp 1500 /cm-¹ 4000 (a) 3000 (b) .OH 2000 HOT (c) OH (d) 1000 NH₂ (e) 500
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Infrared (IR) Spectroscopy: Compound Identification
#### Question 12.2:
**Which compound is consistent with the spectrum shown below?**
#### Interpretation of the IR Spectrum:
The provided IR spectrum is used to identify organic compounds based on their unique absorption patterns.
**Axis Information:**
- The x-axis represents the **wavenumber (cm<sup>-1</sup>)**, ranging from 4000 to 500 cm<sup>-1</sup>. The wavenumber is inversely proportional to wavelength, and it indicates the frequency at which the molecule absorbs IR light.
- The y-axis represents **transmittance (%)**, which ranges from 0 to 100%. High transmittance means low absorption, and low transmittance means high absorption.
**Key Features in the Spectrum:**
1. **Broad Peaks around 3200-3600 cm<sup>-1</sup>:**
- Indicative of O-H or N-H stretching.
2. **Strong Peak near 1700 cm<sup>-1</sup>:**
- Indicative of C=O (carbonyl) stretching.
3. **Multiple Peaks in the Fingerprint Region (1500-500 cm<sup>-1</sup>):**
- Useful for identifying specific functional groups and overall match with compounds but generally more complex.
#### Compounds to Consider:
Below the spectrum, five structural formulas of organic compounds are provided as potential matches:
1. **Compound (a):** An aliphatic compound with a double bond.
2. **Compound (b):** An alcohol.
3. **Compound (c):** A carboxylic acid.
4. **Compound (d):** An amine.
5. **Compound (e):** An ester.
#### Analysis:
Given the broad peak around 3200-3600 cm<sup>-1</sup>, this suggests the presence of an O-H group or N-H group. The strong peak near 1700 cm<sup>-1</sup> indicates the presence of a carbonyl group (C=O).
**Conclusion:**
Based on the IR spectrum, the compound is consistent with the presence of both an O-H group (broad peak around 3200-3600 cm<sup>-1</sup>) and a carbonyl group (sharp peak around 1700 cm<sup>-1</sup>). Therefore, the compound most consistent with the spectrum is **Compound
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