Answered: Etylong Glyol (B) 0.1 02 0.3 ung 05…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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"
A mixture of chloroform (CHCl₃) and acetic acid at 18^oC and 1atm (101.3 kPa) is extracted with water to recover the acid. Fortyfive kg of 35 wt% CHCl₃ and 65 wt% acid is treated with 22.75 kg of water at 18^oC in a one-stage batch extraction. (a) What are the compositions and masses of the raffinate and extract layers? (b) If the raffinate layer from part (a) is extracted again with one-half its weight of water, what are the compositions and weights of the new layers? (c) If all the water is removed from the final raffinate layer of part (b), what will its composition be? Solve this exercise using the following equilibrium data to construct one or more of the types of diagrams .

Etylong Glyol
(B)
0.1
02
0.3
ung
05 Flat
Misbi
Point
as
0.3
Tialine
0.7
0.2
0.1
09
Furtural
Water
(A)
0.7
0.5
Mass fraction furtural
0.6
0.4
0.3
0.2
0.1G
Mans fractien war
Rafina
Mattion ethyleneg

LIQUID-LIQUID EQUILIBRIUM DATA FOR CHCI3-H2O-
CH;COOH AT 18°C AND 1 ATM
Heavy Phase (wt%)
Light Phase (wt%)
CHCI3
Но
CH-COОН
CHCI3
Н-О
CH,COОН
99.01
0.99
0.00
0.84
99.16
0.00
91.85
1.38
6.77
1.21
73.69
25.10
80.00
2.28
17.72
7.30
48.58
44.12
70.13
4.12
25.75
15.11
34.71
50.18
67.15
5.20
27.65
18.33
31.11
50.56
59.99
7.93
32.08
25.20
25.39
49.41
55.81
9.58
34.61
28.85
23.28
47.87

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