Liquid bromine dissolves readily in aqueous NaOH: Br2(€) + 2 NaOH(aq) NaBr(aq) + NaOBr(aq) + H,O(€) Suppose 2.88 × 10-3 mol of Br2(e) is sealed in a glass cap- sule that is then immersed in a solution containing excess NaOH(aq). The capsule is broken, the mixture is stirred, and a measured 121.3 J of heat evolves. In a separate experiment, simply breaking an empty capsule and stirring the solution in the same way evolves 2.34 J of heat. Com- putc the heat cvolvcd as 1.00 mol Br,(l) dissolves in excess NaOH(aq).

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Liquid bromine dissolves readily in aqueous NaOH:
Br2(€) + 2 NaOH(aq)
NaBr(aq) + NaOBr(aq) + H,O(€)
Suppose 2.88 × 10-3 mol of Br2(e) is sealed in a glass cap-
sule that is then immersed in a solution containing excess
NaOH(aq). The capsule is broken, the mixture is stirred,
and a measured 121.3 J of heat evolves. In a separate
experiment, simply breaking an empty capsule and stirring
the solution in the same way evolves 2.34 J of heat. Com-
putc the heat cvolvcd as 1.00 mol Br,(l) dissolves in
excess NaOH(aq).
Transcribed Image Text:Liquid bromine dissolves readily in aqueous NaOH: Br2(€) + 2 NaOH(aq) NaBr(aq) + NaOBr(aq) + H,O(€) Suppose 2.88 × 10-3 mol of Br2(e) is sealed in a glass cap- sule that is then immersed in a solution containing excess NaOH(aq). The capsule is broken, the mixture is stirred, and a measured 121.3 J of heat evolves. In a separate experiment, simply breaking an empty capsule and stirring the solution in the same way evolves 2.34 J of heat. Com- putc the heat cvolvcd as 1.00 mol Br,(l) dissolves in excess NaOH(aq).
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