Li-ion batteries used in automobiles typically use aLiMn2O4 cathode in place of the LiCoO2 cathode found in most Li-ion batteries. (a) Calculate the mass percent lithiumin each electrode material. (b) Which material has ahigher percentage of lithium? Does this help to explainwhy batteries made with LiMn2O4 cathodes deliver lesspower on discharging? (c) In a battery that uses a LiCoO2cathode, approximately 50% of the lithium migrates fromthe cathode to the anode on charging. In a battery thatuses a LiMn2O4 cathode, what fraction of the lithium inLiMn2O4 would need to migrate out of the cathode todeliver the same amount of lithium to the graphite anode?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Li-ion batteries used in automobiles typically use a
LiMn2O4 cathode in place of the LiCoO2 cathode found in most Li-ion batteries. (a) Calculate the mass percent lithium
in each electrode material. (b) Which material has a
higher percentage of lithium? Does this help to explain
why batteries made with LiMn2O4 cathodes deliver less
power on discharging? (c) In a battery that uses a LiCoO2
cathode, approximately 50% of the lithium migrates from
the cathode to the anode on charging. In a battery that
uses a LiMn2O4 cathode, what fraction of the lithium in
LiMn2O4 would need to migrate out of the cathode to
deliver the same amount of lithium to the graphite anode?

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