Label the stereogenic center(s) in each drug as R or S. L-Dopa is used to treat Parkinson's disease (Chapter 1). Ketamine is an anesthetic. Enalapril belongs to a class of drugs called ACE inhibitors, which are used to lower blood pressure. CH3 NHẠC CH,CH,O, a. HO OH COOH HÌNH, L-dopa b. ketamine N H O enalapril Trade name: Vasotec CO₂H
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![Label the stereogenic center(s) in each drug as R or S. L-Dopa is used to treat Parkinson's disease (Chapter 1). Ketamine is an
anesthetic. Enalapril belongs to a class of drugs called ACE inhibitors, which are used to lower blood pressure.
CH3
NHẠC
CH,CH,Oz
a.
HO
OH
COOH
HÌNH,
L-dopa
b.
ketamine
H
enalapril
Trade name: Vasotec
CO₂H](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F40a4521f-2006-4451-a928-5d018e4272d3%2Fe825cf6d-46f8-4aa0-b0da-0d61508bc8e3%2Fv05ggtj_processed.jpeg&w=3840&q=75)
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