л, Br н.ӧ: а. Нӧ: Br CH3CH-CHCH3 CH3CH=CHCH3 н + NH3 b. СH:CH-C%3C—н + :NH, CH3CH2C=C: CHз CH3C CHз с. CH-C —СНCH,CH3 СНCH-CH3 CH3 CH3 CHз CH3 н,ӧ: Н,ӧ" CH2=CCH3 d. CH2-CCH3 Н
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
Draw curved arrows to show the movement of the electrons that result in formation of the given product
![л,
Br
н.ӧ:
а. Нӧ:
Br
CH3CH-CHCH3
CH3CH=CHCH3
н
+ NH3
b. СH:CH-C%3C—н + :NH,
CH3CH2C=C:
CHз
CH3C
CHз
с. CH-C —СНCH,CH3
СНCH-CH3
CH3
CH3
CHз
CH3
н,ӧ:
Н,ӧ"
CH2=CCH3
d. CH2-CCH3
Н](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F0a5ef3a4-7da5-4ad2-862e-0d2a4fc8858e%2F7e961698-c872-4f6a-be2b-ac92853a9001%2F6s96w1g5.jpeg&w=3840&q=75)
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