Keq = 2.94 %3D R II R

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Which conformer in present is greater amount at equilibrium? Is the reaction spontaneous or non spontaneous
H
Keq = 2.94
%3D
R
II
R
Transcribed Image Text:H Keq = 2.94 %3D R II R
Expert Solution
Step 1

Concepts: in cyclohexane ring itself, there can be two conformers  by the ring flipping and Both are equivalent in terms of energy since there are always six hydrogens in axial position and six hydrogens in equatorial position.

However, for substituted cyclohexane the two chair conformations are not equivalent any more. As given above in structure I the R group is at axial position and in Structure II the R group is at equatorial position. Studies show that the conformer II with the equatorial R group is more stable.

This difference in stability is due to the “1,3-diaxal interaction”. In axial R group  conformation, the R group is very close to the axial hydrogens that is one carbon away  and it causes the repulsion between each other that is called the 1,3-diaxal interaction.

This type of repulsion is the same as the gauche steric strain because the R group and the CH are in gauche position. While for equatorial- R group conformer, no such strains applied because the R group and the CH are in anti-position. 

 

steps

Step by step

Solved in 2 steps

Blurred answer
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY