Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Cyclohexane Conformation Question**
**Question 12:** Which is the least stable conformation of cyclohexane?
- a) Boat
- b) Chair
- c) Envelope
- d) All six carbons coplanar
- e) Five carbons coplanar
This question explores the various conformations of cyclohexane and asks which one is the least stable. Cyclohexane can adopt multiple conformations due to the flexibility of its carbon ring. The chair conformation is generally the most stable due to minimal torsional strain, while the boat conformation has more strain. Other conformations like having all or some carbons coplanar introduce additional angle strain, making them less stable compared to the chair conformation.
Expert Solution

Step 1: Introduction
Ring flipping is another process that cyclohexane can go through to switch between the boat and chair conformations. Through a dynamic mechanism called ring flipping, cyclohexane can reduce steric strain and increase stability.
The less stable twist-boat and half-chair conformations, which are frequently seen as intermediates during ring flipping, are among the numerous higher-energy conformations of cyclohexane that can exist in addition to the chair and boat conformations.
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