only parts (v) , (vi) CHE204A (2019)(f) For butadiene (C4H10), the coefficients for the linear combination of atomic orbitals for thetwo lowest energy л-MОs are given below:ΜΟ4/2½1Normalised CoefficientsAtom 3Atom 2+0.3717 -0.3717+0.6015Atom 1+0.6015+0.3717 +0.6015Page 3 of 5Atom 4-0.6015+0.3717(i) Predict the coefficients at each atom for the two highest energy л-MOs (⁄3, ¼4).Justify your solution using diagrams.(ii) Calculate the total л-electron densities on atoms 1, 2, 3 and 4.(iii) Calculate the total -bond order ween atoms 1-2, 2-3 and 3-4(iv) Estimate the total o- and л-bond orders between atoms 1-2, 2-3 and 3-4.(v) How does your solution in (iv) relate to the traditional representation of butadiene witha double-single-double bond structure.MAI

(iv) To find out the total σ- and π-bond order between the atoms 1-2, 2-3 and 3-4 of the butadiene.…

(iv) Estimate the total o- and л-bond orders between atoms 1-2, 2-3 and 3-4. (v) How does your solution in (iv) relate to the traditional representation of butadiene with bond structure. a double-single-double

(iv) Estimate the total o- and л-bond orders between atoms 1-2, 2-3 and 3-4. (v) How does your solution in (iv) relate to the traditional representation of butadiene with bond structure. a double-single-double

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Organometallic Compounds of s- and p- block elements

Organometallic compounds have a minimum of one bond between a metal compound and a carbon atom. Metalloid elements such as silicon, tin, and boron form organometallic compounds which can be utilized in a few commercial chemical reactions.

Question

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only parts (v) , (vi)

CHE204A (2019)
(f) For butadiene (C4H10), the coefficients for the linear combination of atomic orbitals for the
two lowest energy л-MОs are given below:
ΜΟ
4/2
½1
Normalised Coefficients
Atom 3
Atom 2
+0.3717 -0.3717
+0.6015
Atom 1
+0.6015
+0.3717 +0.6015
Page 3 of 5
Atom 4
-0.6015
+0.3717
(i) Predict the coefficients at each atom for the two highest energy л-MOs (⁄3, ¼4).
Justify your solution using diagrams.
(ii) Calculate the total л-electron densities on atoms 1, 2, 3 and 4.
(iii) Calculate the total -bond order ween atoms 1-2, 2-3 and 3-4
(iv) Estimate the total o- and л-bond orders between atoms 1-2, 2-3 and 3-4.
(v) How does your solution in (iv) relate to the traditional representation of butadiene with
a double-single-double bond structure.
MAI

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