Isopropyl ether (E) is used to separate acetic acid (A) from water (W). The liquid-liquid equilibrium data at 25 C and 1 atm are given below: (a) One hundred kilograms of a 30 wt% A-W solution is contacted with 120 kg of ether (E). What are the compositions and weights of the resulting extract and raffinate? What would the concentration of acid in the (ether-rich) extract be if all ether were removed? (b) A solution of 52 kg A and 48 kg W is contacted with 40 kg of E. Calculate the extract and raffinate compositions and quantities.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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Exercice 2:
Isopropyl ether (E) is used to separate acetic acid (A) from water (W). The liquid-liquid
equilibrium data at 25°C and 1 atm are given below: (a) One hundred kilograms of a 30 wt% A-W
solution is contacted with 120 kg of ether (E). What are the compositions and weights of the
resulting extract and raffinate? What would the concentration of acid in the (ether-rich) extract be if
all ether were removed? (b)
Calculate the extract and raffinate compositions and quantities.
solution of 52 kg A and 48 kg W is contacted with 40 kg of E.
LIQUID-LIQUID EQUILIBRIUM DATA FOR
ACETIC ACID (A), WATER (W), AND
ISOPROPANOL ETHER (E) AT 25°C AND 1 ATM
Water-Rich Layer
Ether-Rich Layer
WE% A
Wt% W
Wt% E
Wt% A
W1% W
Wt% E
1.41
97.1
1.49
0.37
0.73
98.9
2.89
95.5
1.61
0.79
0.81
98.4
6.42
91.7
1.88
1.93
0.97
97.1
13.30
84.4
2.3
4.82
1.88
93.3
25.50
71.1
3.4
11.4
3.9
84.7
36.70
58.9
4.4
21.6
6.9
71.5
45.1
9.6
31.1
10.8
58.1
45.30
16.5
36.2
15.1
48.7
46.40
37.1
Transcribed Image Text:Exercice 2: Isopropyl ether (E) is used to separate acetic acid (A) from water (W). The liquid-liquid equilibrium data at 25°C and 1 atm are given below: (a) One hundred kilograms of a 30 wt% A-W solution is contacted with 120 kg of ether (E). What are the compositions and weights of the resulting extract and raffinate? What would the concentration of acid in the (ether-rich) extract be if all ether were removed? (b) Calculate the extract and raffinate compositions and quantities. solution of 52 kg A and 48 kg W is contacted with 40 kg of E. LIQUID-LIQUID EQUILIBRIUM DATA FOR ACETIC ACID (A), WATER (W), AND ISOPROPANOL ETHER (E) AT 25°C AND 1 ATM Water-Rich Layer Ether-Rich Layer WE% A Wt% W Wt% E Wt% A W1% W Wt% E 1.41 97.1 1.49 0.37 0.73 98.9 2.89 95.5 1.61 0.79 0.81 98.4 6.42 91.7 1.88 1.93 0.97 97.1 13.30 84.4 2.3 4.82 1.88 93.3 25.50 71.1 3.4 11.4 3.9 84.7 36.70 58.9 4.4 21.6 6.9 71.5 45.1 9.6 31.1 10.8 58.1 45.30 16.5 36.2 15.1 48.7 46.40 37.1
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