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is it possible for a compound to have an Rf > 1?
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- 4. Given the ¹HNMR spectrum below and that the molecular formula for the molecule is C5H100, what is the molecule? The ratio of the areas of the quartet:triplet is 2:3. TMS 3 2 1 Chemical Shift (ppm) --0Structure?4. IR stretching frequency of C=O in acetic acid is 1720 cm. But, The same in Benzoic acid appears at 1680 cm 1. Explain. 0 11 0 CH₂ / C HO OH acetic acid Benzoic acid
- List from highest to lowest chemical shift in the C-13 NMR spectrum. III II O II, 1, II O III, || | O II, I, II OI II, ||The simulated APT spectrum of a compound with the molecular formula C6H12 is shown. Draw a structure that is consistent with this data.b) Use the C13NMR spectrum below to determine the structural formula for the compound of molecular formula C5H100. Chemical Formula: C5H1,0 140 120 PPM 220 200 180 160 100 80 60 40 20
- 7) The correct structure that corresponds to the spectroscopic data given below is [IR 2720, 1710 1 point cm*1. 1H NMR 9.80(s, 1H), 7.50(dd, J = 8,0Hz, 2Hz, 1H), 7.40(d, J = 2.0Hz, 1H), 6.90(d, J = 8.0Hz, 1H), 3.90(s, 3H), 3.80(s, 3H)] COOH OMe Me CHO OMe OMe CHO OMe OMe COOH OMe MeWhich of the following would not theoretically be seen in the splitting patterns for the 1Hb NMR signals for the following molecule if Jab < Jbc . CH; „Hb H;aC `CH2c-Br A. type b splits type a into a doublet B. type b splits type c into a doublet O C. type a splits type b into a septet then type c splits those into triplets O D. type c splits type b into a triplet then type a splits those into septetsShown below are carbon NMR spectra for various isomers of C5H11Br. Assign structures for the compound that would produce each spectrum.
