In this reduction of aldehyde to carboxylic acids using sodium chlorite, where did the C = O- - H come from ? (highlighted in green), I checked the wiki and it said it came from HCIO2, and oxygen from C = O took the H from HCIO2. Now the question is, how did the HCIO2 formed from the reaction conditions shown above? Did the buffer provide the hydrogen to the ClO2- anion? Oxidation of Carbonyl Compounds aldehydes to carboxylic acids 3 sodium chlorite NaCIO₂ aq. Na₂HPO4 (buffer) C H (+ 2

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In this reduction of aldehyde to carboxylic acids using sodium chlorite, where did the C = O- - H
come from ? (highlighted in green), I checked the wiki and it said it came from HCIO2, and
oxygen from C = O took the H from HCIO2. Now the question is, how did the HCIO2 formed from
the reaction conditions shown above? Did the buffer provide the hydrogen to the CIO2- anion?
Oxidation of Carbonyl Compounds
aldehydes to carboxylic acids
R
RÅH
Н
+H
H
sodium chlorite
NaClO2
aq. Na₂HPO4 (buffer)
2-methyl-2-butene
O-CI=O
HO
R
H-
POH (+ HO-C₁)
HO
R
O
CI-OH
hypochlorous
acid
+
Transcribed Image Text:In this reduction of aldehyde to carboxylic acids using sodium chlorite, where did the C = O- - H come from ? (highlighted in green), I checked the wiki and it said it came from HCIO2, and oxygen from C = O took the H from HCIO2. Now the question is, how did the HCIO2 formed from the reaction conditions shown above? Did the buffer provide the hydrogen to the CIO2- anion? Oxidation of Carbonyl Compounds aldehydes to carboxylic acids R RÅH Н +H H sodium chlorite NaClO2 aq. Na₂HPO4 (buffer) 2-methyl-2-butene O-CI=O HO R H- POH (+ HO-C₁) HO R O CI-OH hypochlorous acid +
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