In the presence of hydrogen sulfide, silver oxidizes to form silver sulfide (silver tarnish). It forms a black film on the surface of silver. 4Ag+2H2S+O2→2Ag2S+2H2O One way to reverse the chemical reaction and turn silver sulfide back into silver is by immersing the silver in an aluminum container filled with a hot solution of sodium bicarbonate. Metals like aluminum have a greater affinity for sulfur than silver. This tarnish-removal method uses a chemical reaction to convert the silver sulfide back into silver, resulting

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

In the presence of hydrogen sulfide, silver oxidizes to form silver sulfide (silver tarnish). It forms a black film on the surface of silver.

4Ag+2H2S+O2→2Ag2S+2H2O

One way to reverse the chemical reaction and turn silver sulfide back into silver is by immersing the silver in an aluminum container filled with a hot solution of sodium bicarbonate. Metals like aluminum have a greater affinity for sulfur than silver.

This tarnish-removal method uses a chemical reaction to convert the silver sulfide back into silver, resulting in no net loss of silver. The reaction between silver sulfide and aluminum takes place in the presence of a sodium bicarbonate (NaHCO3) solution, resulting in the transfer of sulfur atoms from silver to aluminum, freeing the silver metal and forming aluminum sulfide.

The reaction can be summarized as follows: when silver sulfide reacts with aluminum, silver sulfide is reduced to form silver and aluminum is oxidized to form aluminum sulfide.

Complete the balanced chemical equation for the reaction, showing the formation of silver metal from silver sulfide in the presence of aluminum metal.

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY