In the leachate pond the conditions are more acidic causing NH3 to exist as NH4+. NH4+ can react with nitrites in the pond to form the less hazardous N2 and H2O as seen below: NH4+ + NO2–    →   N2 + 2H2O  You want to investigate methods of speeding up this reaction but you first conducted an initial rates test to determine the rate law equation for the reaction.  Using the data in the table below determine the rate law equation for the reaction above.   Experiment Number Initial NH4+ M Initial NO2– Initial Rate (M/s) 1 0.0100 0.200 5.4 x 10 –7 2 0.0400 0.200 21.5 x 10 –7 3 0.200 0.0404 21.6 x 10 –7 4 0.0200 0.200 10.8 x 10 –7 5 0.200 0.0202 10.8 x 10 –7 6 0.200 0.0808 43.3 x 10 –7

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Chapter1: Chemical Foundations
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In the leachate pond the conditions are more acidic causing NH3 to exist as NH4+. NH4can react with nitrites in the pond to form the less hazardous N2 and H2O as seen below:

NH4+ + NO2    →   N2 + 2H2O

 You want to investigate methods of speeding up this reaction but you first conducted an initial rates test to determine the rate law equation for the reaction.  Using the data in the table below determine the rate law equation for the reaction above.

 

Experiment Number

Initial NH4+ M

Initial NO2

Initial Rate (M/s)

1

0.0100

0.200

5.4 x 10 –7

2

0.0400

0.200

21.5 x 10 –7

3

0.200

0.0404

21.6 x 10 –7

4

0.0200

0.200

10.8 x 10 –7

5

0.200

0.0202

10.8 x 10 –7

6

0.200

0.0808

43.3 x 10 –7

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